In this paper, we optimized Number Theoretic Transform (NTT) and random sampling operations on low-end 8-bit AVR microcontrollers. We focused on the optimized modular multiplication with secure countermeasure (i.e., constant timing), which ensures high performance and prevents timing attack and simple power analysis. In particular, we presented combined Look-Up Table (LUT)-based fast reduction techniques in a regular fashion. This novel approach only requires two times of LUT access to perform the whole modular reduction routine. The implementation is carefully written in assembly language, which reduces the number of memory access and function call routines. With LUT-based optimization techniques, proposed NTT implementations outperform the previous best results by 9.0% and 14.6% for 128-bit security level and 256-bit security level, respectively. Furthermore, we adopted the most optimized AES software implementation to improve the performance of pseudo random number generation for random sampling operation. The encryption of AES-256 counter (CTR) mode used for random number generator requires only 3184 clock cycles for 128-bit data input, which is 9.5% faster than previous state-of-art results. Finally, proposed methods are applied to the whole process of Ring-LWE key scheduling and encryption operations, which require only 524,211 and 659,603 clock cycles for 128-bit security level, respectively. For the key generation of 256-bit security level, 1,325,171 and 1,775,475 clock cycles are required for H/W and S/W AES-based implementations, respectively. For the encryption of 256-bit security level, 1,430,601 and 2,042,474 clock cycles are required for H/W and S/W AES-based implementations, respectively.