Comparative analyses of MIL-88B(Fe) and MIL-100(Fe) metal organic frameworks as active anode materials for Li ion batteries

Pukazhselvan, D.; Granadeiro, Carlos M.; Loureiro, Francisco J.A.; Shaula, A.L.; Mikhalev, Sergey M.; Gonçalves, Gil; Fagg, Duncan P.

doi:10.1016/j.electacta.2023.142989

Electrochimica Acta

2023

DOI: 10.1016/j.electacta.2023.142989

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Comparative analyses of MIL-88B(Fe) and MIL-100(Fe) metal organic frameworks as active anode materials for Li ion batteries

D. Pukazhselvan¹,

Carlos M. Granadeiro²,

Francisco J.A. Loureiro³

et al.

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Cited by 13 publications

References 66 publications

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In Situ Electrochemical Tuning of MIL‐88B(V)@rGO into Amorphous V₂O₅@rGO as Cathode for High‐Performance Aqueous Zinc‐Ion Battery

Jia,

Shen,

et al. 2023

Adv Funct Materials

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The design and fabrication of advanced cathode materials with excellent electrochemical properties to match the Zn anode is crucial for the development of aqueous zinc‐ion batteries (ZIBs). Herein the synthesis of MIL‐88B(V)@rGO composites is reported, in which MIL‐88B(V) nanorods are anchored on reduced graphene oxide (rGO) sheets, as cathode for ZIBs, where the graphene oxide induces the formation of small‐size nanorods instead of typical prism morphology. During the initial charge/discharge process, the cathode undergoes an in situ irreversible transformation from MIL‐88B(V) to amorphous V2O5 that acts as active site for the subsequent Zn2+ insertion/extraction. The hierarchical structure of the composites and the amorphous V2O5 provide abundant channels and active sites for Zn2+ diffusion and adsorption. The density functional theory calculation reveals that the rGO sheets have two functions, i.e., to improve the conductivity and to reduce the Zn2+ migration energy barrier. Consequently, the MIL‐88B(V)@rGO cathode exhibits an ultrahigh reversible capacity of 479.6 mAh g−1 at 50 mA g−1 and good rate performance of 263.6 mAh g−1 at 5000 mA g−1, which are superior to metal–organic frameworks (MOFs) cathodes reported in literature. This work may shed a new light to the design and fabrication of MOFs‐based cathodes for aqueous ZIBs.

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In Situ Electrochemical Tuning of MIL‐88B(V)@rGO into Amorphous V₂O₅@rGO as Cathode for High‐Performance Aqueous Zinc‐Ion Battery

Jia,

Shen,

et al. 2023

Adv Funct Materials

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Enhanced cationic dye removal from water media via electrostatic interaction-assisted incorporation of phosphotungstic acid into NH₂-MIL-88B(Fe) through the breathing effect

Royan,

Abbasi,

Hosseini

et al. 2025

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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Bilayer asymmetric-based metal-organic frameworks membrane for blue energy conversion

Tonnah,

Chai,

Khedri

et al. 2024

Desalination

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Comparative analyses of MIL-88B(Fe) and MIL-100(Fe) metal organic frameworks as active anode materials for Li ion batteries

Cited by 13 publications

References 66 publications

In Situ Electrochemical Tuning of MIL‐88B(V)@rGO into Amorphous V₂O₅@rGO as Cathode for High‐Performance Aqueous Zinc‐Ion Battery

In Situ Electrochemical Tuning of MIL‐88B(V)@rGO into Amorphous V₂O₅@rGO as Cathode for High‐Performance Aqueous Zinc‐Ion Battery

Enhanced cationic dye removal from water media via electrostatic interaction-assisted incorporation of phosphotungstic acid into NH₂-MIL-88B(Fe) through the breathing effect

Bilayer asymmetric-based metal-organic frameworks membrane for blue energy conversion

Contact Info

Product

Resources

About

Comparative analyses of MIL-88B(Fe) and MIL-100(Fe) metal organic frameworks as active anode materials for Li ion batteries

Cited by 13 publications

References 66 publications

In Situ Electrochemical Tuning of MIL‐88B(V)@rGO into Amorphous V2O5@rGO as Cathode for High‐Performance Aqueous Zinc‐Ion Battery

In Situ Electrochemical Tuning of MIL‐88B(V)@rGO into Amorphous V2O5@rGO as Cathode for High‐Performance Aqueous Zinc‐Ion Battery

Enhanced cationic dye removal from water media via electrostatic interaction-assisted incorporation of phosphotungstic acid into NH₂-MIL-88B(Fe) through the breathing effect

Bilayer asymmetric-based metal-organic frameworks membrane for blue energy conversion

Contact Info

Product

Resources

About

In Situ Electrochemical Tuning of MIL‐88B(V)@rGO into Amorphous V₂O₅@rGO as Cathode for High‐Performance Aqueous Zinc‐Ion Battery

In Situ Electrochemical Tuning of MIL‐88B(V)@rGO into Amorphous V₂O₅@rGO as Cathode for High‐Performance Aqueous Zinc‐Ion Battery