Absorption thermal energy storage (ATES) is significant for renewable/waste energy utilization in buildings. The ATES systems using ionic liquids (ILs) are explored to avoid crystallization and enhance the performance. Property model and cycle model have been established with verified accuracies. Based on the preliminary screening, seven ILs are found feasible to be ATES working fluids, while four ILs ([DMIM][DMP], [EMIM][Ac], [EMIM][DEP], and [EMIM][EtSO 4 ]) have been selected for detailed comparisons. The coefficient of performance (COP) and energy storage density (ESD) of the ATES using different H 2 O/ILs are compared with H 2 O/LiBr. Results show that the operating temperatures of LiBr are constrained by crystallization, limiting the COPs and ESDs under higher generation temperatures and lower condensation temperatures. With varying T g , [DMIM][DMP] yields higher COPs with T g above 100°C and [EMIM][Ac] yields comparable ESDs (67.7 vs 67.1 kWh/m 3) with T g around 120°C, as compared with LiBr. The maximum COP is 0.745 for [DMIM][DMP]. With varying T c , [DMIM][DMP] yields higher COPs with T c below 38°C and [EMIM][Ac] yields higher ESDs with T c below 33°C, as compared with LiBr. The maximum ESD is 87.5 kWh/m 3 for [EMIM][Ac]. Nomenclature: B i , second virial coefficient of species i, cm 3 /mol; C p,IL , molar heat capacity of ionic liquid, J/(mol•K); f , cycle circulation ratio; H, molar enthalpy, J/mol; h in , inlet specific enthalpy, kJ/kg; h out , outlet specific enthalpy, kJ/kg; m in , inlet mass flow rate, kg/s; m out , outlet mass flow rate, kg/s; m r , refrigerant mass flow rate, kg/s; M s , solution mass, kg; M r , refrigerant mass, kg; p, system pressure, kPa; p S i , saturated vapor pressure of species i, kPa; Q, heat duty, kW; Q e , evaporator heat duty, kW; Q g , generator heat duty, kW; R, universal gas constant, J/(mol•K); T, temperature,°C or K; T a , absorption temperature,°C; T c , condensation temperature,°C; T e , evaporation temperature,°C; T g , generation temperature,°C; V L i , saturated molar liquid volume of species i, cm 3 /mol; V s , solution tank volume, m 3 ; V r , refrigerant tank volume, m 3 ; W, power, kW; W p , power of pump, kW; X i , liquid molar fraction of species i, mol/mol; x, refrigerant mass fraction, kg/kg; x in , inlet refrigerant mass fraction, kg/kg; x out , outlet refrigerant mass fraction, kg/kg; x s , refrigerant mass fraction in the strong solution, kg/kg; x w , refrigerant mass fraction in the weak solution, kg/kg; Y i , vapor molar fraction of species i, mol/mol; α, τ, adjustable parameters of the activity model; η e , electricity generation efficiency; ρ, density, kg/m 3 ; γ i , activity coefficient of species i; Φ i , correction factor of species i; ΔH mix , mixing enthalpy of the solution,