Comparative electrochemical study of N-(4-aminophenyl) and N-(4-hydroxyphenyl)benzenesulfonamide derivatives

Talebi, Mohammad Reza; Nematollahi, Davood; Massah, Ahmad Reza

doi:10.1016/j.electacta.2023.142499

Cited by 6 publications

(2 citation statements)

References 46 publications

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“…These predictions, as well as investigating the reactivity of the target molecules, determining the rate of chemical reactions and assessment the mechanism of the electrode process, are possible by performing voltammetric and coulometric experiments on the raw materials and, on the products. [72] Another feature of electrosynthesis is the ability to control reaction thermodynamics and kinetics using electrode potential. We have shown that using the controlled potential The method as a highly selective tool, a specific compound can be selectively oxidized or reduced among several substances using an appropriately chosen potential.…”

Section: Discussionmentioning

confidence: 99%

Electrochemical Synthesis of Sulfonamide Derivatives: Electrosynthesis Conditions and Reaction Pathways

Talebi,

Nematollahi

2024

ChemElectroChem

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In 2014, the World Health Organization called drug resistance to antibiotics a “major global threat”. Therefore, the ever‐increasing human need for new antibiotics with greater effectiveness and fewer side effects is a necessity. Meanwhile, sulfonamides are among the most widely used antibiotics in the world. In this review, attention has been paid to the key points raised in various papers in the field of electrosynthesis of these compounds, considering their positive and negative aspects, including interaction as much as possible with the principles of green chemistry and the absence of environmental risks, low cost and the versatility and scalability of the method used along with acceptable efficiency. In the following, we will discuss research focused on the synthesis of sulfonamide derivatives based on the oxidation or reduction of various compounds which take place on the working electrode surface.

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Section: Discussionmentioning

confidence: 99%

Electrochemical Synthesis of Sulfonamide Derivatives: Electrosynthesis Conditions and Reaction Pathways

Talebi,

Nematollahi

2024

ChemElectroChem

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“…Benzenesulfonamide (BSA) is a widely used compound in pharmaceuticals, agrochemicals, and material science [ 18 , 19 , 20 , 21 , 22 ]. Its characteristics have been the subject of numerous studies due to its importance as a building block for various applications [ 23 , 24 , 25 , 26 ]. Surprisingly, despite its importance, solubility has rarely been measured [ 27 , 28 ].…”

Section: Introductionmentioning

confidence: 99%

Finding the Right Solvent: A Novel Screening Protocol for Identifying Environmentally Friendly and Cost-Effective Options for Benzenesulfonamide

2023

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This study investigated the solubility of benzenesulfonamide (BSA) as a model compound using experimental and computational methods. New experimental solubility data were collected in the solvents DMSO, DMF, 4FM, and their binary mixtures with water. The predictive model was constructed based on the best-performing regression models trained on available experimental data, and their hyperparameters were optimized using a newly developed Python code. To evaluate the models, a novel scoring function was formulated, considering not only the accuracy but also the bias–variance tradeoff through a learning curve analysis. An ensemble approach was adopted by selecting the top-performing regression models for test and validation subsets. The obtained model accurately back-calculated the experimental data and was used to predict the solubility of BSA in 2067 potential solvents. The analysis of the entire solvent space focused on the identification of solvents with high solubility, a low environmental impact, and affordability, leading to a refined list of potential candidates that meet all three requirements. The proposed procedure has general applicability and can significantly improve the quality and speed of experimental solvent screening.

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Boosted electrocatalytic oxidation of organophosphorus pesticides by a novel high-efficiency CeO2-Doped PbO2 anode: An electrochemical study, parameter optimization and degradation mechanisms

Roshani,

Nematollahi,

Ansari

et al. 2024

Chemosphere

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Comparative electrochemical study of N-(4-aminophenyl) and N-(4-hydroxyphenyl)benzenesulfonamide derivatives

Cited by 6 publications

References 46 publications

Electrochemical Synthesis of Sulfonamide Derivatives: Electrosynthesis Conditions and Reaction Pathways

Electrochemical Synthesis of Sulfonamide Derivatives: Electrosynthesis Conditions and Reaction Pathways

Finding the Right Solvent: A Novel Screening Protocol for Identifying Environmentally Friendly and Cost-Effective Options for Benzenesulfonamide

Boosted electrocatalytic oxidation of organophosphorus pesticides by a novel high-efficiency CeO2-Doped PbO2 anode: An electrochemical study, parameter optimization and degradation mechanisms

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