“…The first spectral range contains the peaks at approximately 265, 336, 430, 610, and 660 cm À1 , which are fingerprints of TiC x , TiN x , TiC x N y , and TiO x compounds. [1,47,48] Recent reports on the laser ablation of Ti target in an organic solvent indicated that no peaks were present in the spectral range between 100 and 1000 cm À1 . [1] As the stoichiometric titanium carbide does not have active Raman modes in the spectral region below 1000 cm À1 , the authors concluded that only 1) 1.4 J cm À2 , (2) 2.8 J cm À2 , (3) 4.2 J cm À2 , (4) 5.6 J cm À2 , (5) 11.2 J cm À2 , and (6) 22.4 J cm À2 .…”