Comparative Studies of Crystalline Orientation and Morphology of Injection Molded Polyolefin Parts

Abstract

We have studied the structural characteristics of the cross-sections of injection molded parts of various crystalline polyolefins including polyethylene (PE), isotactic polypropylene (PP), isotactic poly(butene-1) (PB1) and isotactic poly(4-methylpentene-1) (P4MP1). Polarized light microscopy, birefringence and wide angle x-ray diffraction pole figure analysis were used to investigate the samples. In most cases, high orientations were observed near the mold wall and isotropic molded part cores were found. However, highly oriented mold core regions were found in P4MP1. Significantly different types of crystalline orientation near the mold wall were observed among the various polyolefins. We represent the development of these differences through the components of a crystalline orientation tensor which represent changes in the state of orientation between melts in the mold prior to crystallization and the final crystalline molded part.