Comparative study of the effect of some macro-molecules and some simple molecules on dropping mercury electrode capacity

Gupta, Sandeep

doi:10.1007/bf01781995

Kolloid-Zeitschrift

1954

DOI: 10.1007/bf01781995

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Comparative study of the effect of some macro-molecules and some simple molecules on dropping mercury electrode capacity

Sandeep Gupta

Abstract: Band 137 Heft2/3(1954) ] Gupta, Study of the Effect of Some Macro-Molecules 87

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Cited by 12 publications

References 10 publications

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Early Polarographic Studies on Proteins

Heyrovský

2004

Electroanalysis

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The first effects of proteins observed with the dropping mercury electrode were catalytic, due to evolution of hydrogen in weakly alkaline solutions. Catalytic lowering of hydrogen overvoltage in presence of cobalt ions, the socalled Brdicka reaction, became the main means for polarographic study of proteins. Apart from that, polarography has been used for following proteins in their adsorption on the electrode surface, in their anodic reaction with mercury at positive potentials, in reduction of the disulfidic bonds of their components, in their complexation with metallic ions in the solution, in electrode reactions of their prosthetic groups and in antigen-antibody interactions. Our review is limited to applications of the dropping mercury electrode.

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Early Polarographic Studies on Proteins

Heyrovský

2004

Electroanalysis

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Das Verhalten der Kaliumxanthogenate bei der Wechselstrompolarographie nach BREYER

Pötsch

Schwabe

1962

J. Prakt. Chem.

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Einleitend wird kurz das Prinzip der BREYERschen Wechselstrompolarographie mitgeteilt, dann wird das Zustandekommen der tensammetrischen und der durch Redoxprozesse bedingten Maxima erläutert. Es wurde das polarographische Verhalten der Kaliumxanthogenate bei der Überlagerung einer konstanten Wechselspannung nach BREYER untersucht und gedeutet. Zur Bestimmung kleiner Xanthogenatkonzentrationen (10−5 M) wurde die Konzentrationsabhängigkeit der Wechselstromstärke der Maxima bei konstanter Gleichspannung benutzt (Tensampermetrie).

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Study of the effect of some macro-molecules on transfer coefficient of electrode processes

Agarwal¹

1962

Kolloid-Z.u.Z.Polymere

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Comparative study of the effect of some macro-molecules and some simple molecules on dropping mercury electrode capacity

Abstract: Band 137 Heft2/3(1954) ] Gupta, Study of the Effect of Some Macro-Molecules 87

Cited by 12 publications

References 10 publications

Early Polarographic Studies on Proteins

Early Polarographic Studies on Proteins

Das Verhalten der Kaliumxanthogenate bei der Wechselstrompolarographie nach BREYER

Study of the effect of some macro-molecules on transfer coefficient of electrode processes

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