Abstract. Land use is recognized to impact soil geochemistry on the centennial to millennial timescale, with implications for the distribution and stability
of soil organic carbon (SOC). Young volcanic soils in tropical areas are subject to much faster pedogenesis, noticeable already on the centennial or
even decadal timescale. As land use is a recognized factor for soil formation, it is thus conceivable that even relatively recent land use conversion in
such areas would already bear a significant impact on the resulting formed soils., e.g., in terms of content of pedogenic oxides. Very scarce
observational evidence exists, so such indirect implications of land use on SOC cycling are largely unknown. We here investigated SOC fractions,
substrate-specific mineralization (SOC or added plant residue), and net priming of SOC as a function of forest or agricultural land use on Indonesian
volcanic soils. The content of oxalate-extracted Al (Alo) correlated well with organic carbon (OC) associated with sand-sized aggregates,
particularly in the subsoil. The proportion of SOC in sand-sized ultrasonication-resistant (400 J mL−1) aggregates was also higher in
agricultural land use compared to pine forest land use, and a likewise contrast existed for Alo. These combined observations suggest that enhanced
formation of Al (hydr)oxides promoted aggregation and physical occlusion of OC. This was, importantly, also consistent with a relatively lesser
degradability of SOC in the agricultural sites, though we found no likewise difference in degradability of added 13C-labeled ryegrass or
in native SOC priming between the pine forest and agricultural land uses. We expected that amorphous Al content under agricultural land use
would mainly have promoted mineral association of SOC compared to under pine forest land use but found no indications for this. Improved small-scale
aggregation of tropical Andosols caused by conversion to agriculture and high carbon input via organic fertilizer may thus partially counter the
otherwise expectable decline of SOC stocks following cultivation. Such indirect land use effects on the SOC balance appeared relevant for correct
interpretation and prediction of the long-term C balance of (agro)ecosystems with soil subject to intense development, like the here-studied tropical Andosols.