Key Points: A new well provide the opportunity of a reappraisal of a persistent regional H 2 production in intracontiental settings, in Kansas. Two different origins are suggested for H 2 production in intra-cratonic context: a crustal origin, a surficial origin. Hypotheses of two H 2 are supported by geochemical properties of associated gases, by water associated and completion story of the well.2
AbstractA geochemical study of gas coming from three wells in northeastern Kansas supplements previous studies from the 1980s and points to a persistent regional phenomenon of H 2 production. In 2008, a new well showed, just after drilling, a dry gas phase with more than 80 mole % of H 2 , followed by a water production associated with gas. This gas is mainly composed of N 2 , He, H 2 and occasionally CH 4 , with changing proportions through time. A drastic decrease in H 2 at the well was observed since the aquifer is produced, along with occasional recharges in H 2 evidenced notably in the early phases of gas sampling. We demonstrate that this evolution of gas composition is closely associated to the well completion story. Accordingly, two distinct origins of H 2 are proposed: (1) water reduction associated to iron oxidation in the Precambrian basement (deep crustal H 2 ); (2) reactions occurring in the tubing, primarily attributed to a high Fe 2+ content and organic carbon (DOC=4.1 mg.L -1 ) dissolved in the water. The low δD values averaging -760 ‰ are attributed to low temperature processes, in agreement with both the hypothesis. Furthermore, the suggested origins are supported by the observed gas associations: (a) deep crustal H 2 with radiogenic gases ( 4 He and 40 Ar) and metamorphic N 2 ( 15 N averaging +2.5‰); (b) surficial H 2 with methane produced in the sedimentary aquifer and the tubing by methanogenic organisms.