Comparison of Cyanide and Carbon Monoxide as Ligands in Iron(II) Porphyrinates

Li, Jianfeng; Noll, Bruce C.; Schulz, Charles E.; Scheidt, W. Robert

doi:10.1002/ange.200901434

Cited by 6 publications

(1 citation statement)

References 34 publications

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“…In fact, Chen [106] explains that the relationship is well known (distinguished) and includes several parts (it is a system). "The dative CO-FePc bond is known to be formed via σ-donation from the CO 5σ orbital and π-back donation from Fe dπ [106][107][108][109][110]. " Indeed, several research studies further explore what is referred to in DSRP Theory as an "RDS" (A Relationship-Distinction-System) [111].…”

Section: Recursivementioning

confidence: 99%

A Literature Review of the Universal and Atomic Elements of Complex Cognition

Cabrera,

Cabrera

2023

Journal of Systems Thinking

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This paper posits that universal atomic elements exist that underlie complex cognition. At its core, constructs are born of the dynamics of thinking operating on information. This elemental understanding of the structural underpinnings - and the dynamics between and among the elements - provides insight into the value of thinking and awareness of one’s thinking to everyday life and scientific inquiry. Knowledge of the structural and dynamical properties of human thought leads to generative, purposeful, and predictive cognitive acts that evolve one’s thinking. As a result, our mental models (comprised of information and thinking) of how systems work are better aligned with how they exist in the real world. This alignment yields better solutions, innovation and results. Continued inquiry into the universality of these structural elements has significant potential to advance understanding across a wide variety of academic disciplines. In other words, the study of cognition is deemed synonymous with the evolution of science and knowledge itself.

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Section: Recursivementioning

confidence: 99%

A Literature Review of the Universal and Atomic Elements of Complex Cognition

Cabrera,

Cabrera

2023

Journal of Systems Thinking

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Schuldig gesprochen – ein Beweis für die “Nicht‐Unschuld” des Cyanidliganden

Kaim

2011

Angewandte Chemie

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Über drei Jahrhunderte nach der Erzeugung von CN− in der ersten synthetischen Koordinationsverbindung wurde nun das nicht‐unschuldige Redox‐Verhalten des Cyanidliganden in M3[Co(CN)3] (M=Ba oder Sr) eindeutig belegt. Das 18‐Valenzelektronen‐Komplexion [Co(CN)3]6− besteht laut strukturellen und spektroskopischen Untersuchungen aus Co−I mit abgeschlossener d‐Schale und drei teilreduzierten Cyanid‐Liganden mit der Ladung −5/3.

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“Guilty” Verdict—Evidence for the Noninnocence of Cyanide

Kaim

2011

Angew Chem Int Ed

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Comparison of Cyanide and Carbon Monoxide as Ligands in Iron(II) Porphyrinates

Cited by 6 publications

References 34 publications

A Literature Review of the Universal and Atomic Elements of Complex Cognition

A Literature Review of the Universal and Atomic Elements of Complex Cognition

Schuldig gesprochen – ein Beweis für die “Nicht‐Unschuld” des Cyanidliganden

“Guilty” Verdict—Evidence for the Noninnocence of Cyanide

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