2002
DOI: 10.1063/1.1484388
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Comparison of electronic decay of valence ionized fluorinated carbanions and their acids

Abstract: Articles you may be interested inEffect of electron correlation and shape resonance on photoionization from the S1 and S2 states of pyrazine J. Chem. Phys. 137, 194314 (2012); 10.1063/1.4765374 Valence and inner-valence shell dissociative photoionization of CO in the 26-33 eV range. I. Ion-electron kinetic energy correlation and laboratory frame photoemission Electron propagator theory calculations of molecular photoionization cross sections: The first-row hydridesThe ionization and double-ionization spectr… Show more

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Cited by 7 publications
(5 citation statements)
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“…26 Further we would like to point out studies of electronic decay after inner-valence ionization of CN −38 and of fluorinated carbanions and their acids. 39 ICD of inner-valence holes in clusters is ultrafast, typically taking place on a time scale of the order of 10 fs (see Ref. 40 for a review).…”
Section: Electronic Decay Processes In Weakly Bound Systemsmentioning
confidence: 99%
See 1 more Smart Citation
“…26 Further we would like to point out studies of electronic decay after inner-valence ionization of CN −38 and of fluorinated carbanions and their acids. 39 ICD of inner-valence holes in clusters is ultrafast, typically taking place on a time scale of the order of 10 fs (see Ref. 40 for a review).…”
Section: Electronic Decay Processes In Weakly Bound Systemsmentioning
confidence: 99%
“…See Fig. 2(b) 39 ICD of inner-valence holes in clusters is ultrafast, typically taking place on a time scale of the order of 10 fs (see Ref. 40 for a review).…”
Section: Electronic Decay Processes In Weakly Bound Systemsmentioning
confidence: 99%
“…8,9 The question thus arises: Is molecular electronic decay following valence ionization limited to neutral (and anionic) valence ionized cluster systems? Furthermore, some molecular systems, in particular anionic systems, also show electronic decay following valence ionization, but via a different decay mechanism.…”
Section: Introductionmentioning
confidence: 99%
“… 420 They considered ICD in small ammonia clusters, which is initiated by the removal of a 2s electron from one of the nitrogen atoms. Since adding or removing a proton to a molecular cluster results in large shifts in ionization energies, 421 they were able to demonstrate that protonating of an ammonia cluster inhibits ICD and can even lead to the closing of all ICD channels. Alternatively, deprotonating the cluster increases the number of ICD channels and, correspondingly, the ICD efficiency.…”
Section: Systems and Applicationsmentioning
confidence: 99%