“…Fe-based amorphous alloys and thermal spray coatings are perhaps the most important system for possible applications because of the low cost of iron, and the relatively high strength and hardness of Fe-based amorphous alloys Sunol et al;2001). Extensive research has been carried out on the mechanical alloying of Fe-based amorphous alloys including binary Fe-B, Fe-Cr, and Fe-Zr (Schuh et al;, ternary Fe-Zr-B (Suryanarayana, 2001(Suryanarayana, , 2004 and Fe-(B, P, Si) with various negative heats of mixing.…”