2006
DOI: 10.1016/j.jcis.2006.04.037
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Comparison of isotherms for the ion exchange of Pb(II) from aqueous solution onto homoionic clinoptilolite

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Cited by 65 publications
(24 citation statements)
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“…Besides that, lead was selected in this work, because of its large ionic radius, because it forms a monovalent ion (Pb 2+ + H 2 O → Pb(OH) + ) and because it acts as a borderline acid in comparison with the hard acids Fe 3+ and Na + . In lead exchange experiments both on not-pretreated and homoionic sodic clinoptilolites, selectivity varied [14,21,22,24,25] even for similar Si/Al ratios and comparable conditions. Exchange isotherms of lead presented concave types "a" and "d" according to Breck [36], whereas iron exchange isotherms have been reported with sigmoid type "b" [23].…”
Section: Parent and Exchanged Tuffsmentioning
confidence: 95%
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“…Besides that, lead was selected in this work, because of its large ionic radius, because it forms a monovalent ion (Pb 2+ + H 2 O → Pb(OH) + ) and because it acts as a borderline acid in comparison with the hard acids Fe 3+ and Na + . In lead exchange experiments both on not-pretreated and homoionic sodic clinoptilolites, selectivity varied [14,21,22,24,25] even for similar Si/Al ratios and comparable conditions. Exchange isotherms of lead presented concave types "a" and "d" according to Breck [36], whereas iron exchange isotherms have been reported with sigmoid type "b" [23].…”
Section: Parent and Exchanged Tuffsmentioning
confidence: 95%
“…On the same subject, lead, various research groups have studied cation exchange equilibria in lead-clinoptilolite batch systems [11][12][13][14][15][16][17][18][19][20][21][22][23][24][25] and for heulandite, the isostructural aluminosilicate of clinoptilolite, modification by lead has been reviewed by Inglezakis [26]. However, the adsorption properties of lead-modified clinoptilolites have not been studied extensively.…”
Section: Introductionmentioning
confidence: 99%
“…The natural zeolite was characterized in previous works(Berber-Mendoza et al 2006;Leyva-Ramos et al 2008). The XRD pattern of the natural zeolite revealed that the zeolite was chiefly composed of clinoptilolite, and it contained impurities such as quartz, calcite and feldspar(Leyva- Ramos et al 2008).…”
mentioning
confidence: 99%
“…The XRD pattern of the natural zeolite revealed that the zeolite was chiefly composed of clinoptilolite, and it contained impurities such as quartz, calcite and feldspar(Leyva- Ramos et al 2008). The chemical composition of the natural zeolite is given inTable 1(Berber-Mendoza et al 2006). The natural zeolite had a Si/Al molar ratio of 6.89.…”
mentioning
confidence: 99%
“…The maximum biosorption capacities of Cu(II) and Pb(II) onto P. pseudoalcaligenes cell reach 0.443 and 1.12 mmol/g dry cells, respectively, at pH 5. The most common adsorbents for heavy metals are ionexchange resins, either synthetic or natural solid resin that are effective to remove metals, such as cation-exchange resin Purolite C100 and clinoptilolite ion-exchange resin with adsorption capacities between 0.04 and 1.4 mmol/g for Cu(II) and Pb(II) ions at pH 4-5 (Berber- Mendoza et al 2006;Abo-Farha et al 2009;Fu and Wang 2011). Compared with these conventional ion-exchange resins, the binding capacities of P. pseudoalcaligenes cells for the studied metals are high enough for use in the removal of heavy metals from solution.…”
Section: Metal Biosorptionmentioning
confidence: 99%