Evaluating environmental conditions that trigger fire-fighting equipment is one of the primary design tasks that have to be taken into account when engineering electrical systems supplying such devices. All of the solutions are aimed at, among others, preserving environmental parameters in a building being on fire for an assumed time and at a level enabling safe evacuation. These parameters include temperature, thermal radiation, visibility range, oxygen concentration, and environmental toxicity. This article presents a new mathematical model for heat exchange between the environment and an electric cable under thermal conditions exceeding permissible values for commonly used non-flammable installation cables. The method of analogy between thermal and electrical systems was adopted for modelling heat flow. Determining how the thermal conductivity of the cable and the thermal capacity of a conductor-insulation system can be applied to calculate the wire temperature depending on the heating time t and distance x from the heat source is discussed. Thermal conductivity and capacity were determined based on experimental tests for halogen-free flame-retardant (HFFR) cables with wire cross-sections of 2.5, 4.0, and 6.0 mm2. The conducted experimental tests enable verifying the results calculated by the mathematical model.