In pursuing advancing solar energy systems, this research uniquely occupies a position at the intersection of photovoltaic (PV) efficiency, innovative design and aesthetic integration into urban landscapes. This study explores the potential of thin solar cells applied to spherical and hemispherical surfaces and the influence of temperature variations throughout the day. By conducting a comprehensive analysis of voltage–current diagrams, the study deciphers the intricate interconnections of spherical geometries and their response to external thermal impacts, elucidating their subsequent effects on energy conversion efficiency. Moreover, it delved into the dynamics of connecting multiple spherical modules, unveiling their potential to form artistic and utilitarian constructs such as solar trees and architectural embellishments. The findings indicate that while spherical configurations provide superior aesthetics and a power generation profile comparable to solar tracking systems, hemispherical configurations offer a 32% increase in efficiency compared with the spherical configuration and a notable reduction in land footprint. This research underscores the importance of striking a balance between aesthetic appeal, efficiency and land utilization, providing valuable insights for the future of PV technology integration into urban and agricultural landscapes.