Comparison of the mechanical properties and electrochemical behavior of TiN and CrN single-layer and CrN/TiN multi-layer coatings deposited by PVD method on a dental alloy

Mansoor, Nidhal Sahib; Fattah‐alhosseini, Arash; Elmkhah, Hassan; Shishehian, Arash

doi:10.1088/2053-1591/ab640d

Cited by 20 publications

(7 citation statements)

References 36 publications

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“…Multilayer coatings have received specific attention in order to solve these problems. CAE-PVD coating has received much attention because of the unique characteristics that gives to the coating structure [23][24][25][26][27][28]. Creating coatings with a dense, uniform, continuous structure, excellent adhesion to the substrate, good control on the morphology of coatings during deposition using parameter modification, possibility of coating for high melting point coatings and above all possibility of deposition in various coating rates ranging from one nanometer per minute to several micrometers per hours are the remarkable features of the CAE method [29][30][31].…”

Section: Introductionmentioning

confidence: 99%

Comparing electrochemical behavior of applied CrN/TiN nanoscale multilayer and TiN single-layer coatings deposited by CAE-PVD method

Fazel

Elmkhah

Fattah‐alhosseini

et al. 2020

Journal of Asian Ceramic Societies

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The main goal of this study is to compare the electrochemical behavior of CrN/TiN multilayer coating and TiN single-layer coating applied by cathodic arc evaporation (CAE)-physical vapor deposition (PVD) on the substrate of Ti-6Al-4 V in Hank's solution. So, a TiN single-layer coating was formed using PVD method as well as CrN/TiN multilayer coating under totally the same conditions including deposition temperature, working pressure, bias voltage, cathode current and deposition time. To identify the phases in the coatings, X-ray diffraction (XRD) was utilized in order and field emission scanning electron microscopy (FE-SEM) was used in order to study the microstructure of coating. Potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) tests were also carried out for corrosion measurements. In the corrosion evaluation, the PDP and EIS tests were performed for the samples after immersion in Hank's solution for 24 hours to reach the steady state. The obtained results from PDP curves showed that the specimen with CrN/TiN multilayer coating exhibited better corrosion behavior than the TiN single-layer coatings. This improvement in corrosion resistance is probably due to the high density of the layers in the CrN/TiN multilayer coating that prevents the penetration of the corrosive solution to the substrate.

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Section: Introductionmentioning

confidence: 99%

Comparing electrochemical behavior of applied CrN/TiN nanoscale multilayer and TiN single-layer coatings deposited by CAE-PVD method

Fazel

Elmkhah

Fattah‐alhosseini

et al. 2020

Journal of Asian Ceramic Societies

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“…A detailed description of the PVD processing can be found in ref. [5]. The monolayer and nanostructured coatings were precipitated on nickelchromium dental alloys after being cleaned with the bombardment of argon ions (Ar) at low energy, followed by the high energy of both Ti and Cr ion bombardment.…”

Section: Coating Depositionmentioning

confidence: 99%

“…A nickel-chromium dental alloy can be described as a non-precious alloy currently used at dental prosthetics laboratories [1][2][3][4][5]. Being allergic to Ni compounds is a disadvantage of the Ni-Cr alloys seen in a significant number of people, which were 5-10 times more often, in the case of women rather than men [6,7].…”

Section: Introductionmentioning

confidence: 99%

Electrochemical behavior of TiN, CrN and TiN/CrN nanostructured coatings on the nickel-chromium alloy used in dental fixed prosthesis

Mansoor

Fattah‐alhosseini

Elmkhah

et al. 2020

Journal of Asian Ceramic Societies

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The aim of this research is the evaluation of the influence of TiN, CrN and TiN/CrN nanostructured coatings on corrosion resistance of nickel-chromium dental alloy in artificial saliva environment with two pH levels (3.0 and 6.5). Nickel-chromium alloy tested in this study were more resistant to corrosion in artificial saliva conditioning media when coated with different types of coating materials, as compared to uncoated alloy. The electrochemical measurements propose that the alloy with CrN coating has shown a high corrosion resistance in different pH levels. The superior passivation of CrN monolayer coating in modified Fusayama artificial saliva solution may be concluded from two essential factors, passive range, and corrosion current density. The passive range is well-developed, while the corrosion current density is much lower if compared to the other groups. Also, the Nyquist and polarization plots reveal that TiN, CrN and TiN/CrN nanostructured coatings have an excellent corrosion resistance which is considered much higher if compared to the substrate. The values of corrosion current density for CrN nanostructured coating in artificial saliva environment with two pH levels of 3.0 and 6.5 were 1.373 × 10 −8 and 5.416 × 10 −8 A.cm −2 , respectively that were the lowest corrosion current density values among the other samples.

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“…Moreover, the surface properties of nickel-based dental (Ni-Cr) alloy can be improved by different strategies and PVD techniques, not just by state-of-the-art literature searching (Mansoor et al 2021, Banaszek et al 2022. Using cathodic arc evaporation, Nidhal Sahib Mansoor studied the microstructure, corrosion, and wear behavior of TiN, CrN, and TiN-CrN composite coatings on Cr-Ni alloys (Mansoor et al 2019a, 2019b, Mansoor et al 2020. ZekaiTek investigated the mechanical properties of TiN coatings on Ni-Cr alloys using physical vapor deposition, ion implantation, and micro-pulse plasma nitriding techniques (Tek et al 2002, Tek et al 2005.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of biocompatible coating on Ni-Cr alloy by cathodic cage plasma processing technique as anti-pathogenic bacteria for medicinal applications

Asghar

Yousaf²,

Huwaimel

et al. 2023

Phys. Scr.

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The current research work reports the deposition of titanium-based multilayer coating (TiO/TiN) on Ni-Cr metallic alloy by a cathodic cage plasma processing technique using a titanium cage along with various combinations of gas mixtures i.e., N2-H2-Ar-O2 at 400 oC. The samples were characterized using X-ray photoelectron spectroscopy (XPS), which revealed the surface coating of TiO/TiN with Ti 2p at 462 eV, N 1s at 406 eV and O 1s at 530.09 eV. The X-ray diffraction (XRD) analysis confirmed the polycrystalline structure in the titanium-based coating with (111) for TiO/TiN and a crystallite size of 32nm. Scanning electron microscopy (SEM) and X-ray dispersive spectroscopy (EDX) analysis of titanium-based TiO/TiN coatings was well correlated with the above mentioned findings. Corrosion analysis using polarization potentio-dynamic plots (PDP) and electrochemical impedance spectroscopy (EIS) revealed a significant improvement in various corrosion parameters like corrosion resistance, corrosion rate, surface porosity, corrosion protection efficiency, impedance, and charge transfer resistance. A spectrophotometer was used to measure the leaching of toxic ions (Ni, Cr) from untreated and treated specimens in NaCl electrolyte. Findings revealed efficient antibacterial activity of TiO/TiN-coated specimens against E. coli and S. aureus as compared to untreated samples. This work will be helpful for understanding the biological features of metallic materials for medicinal applications.

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Comparison of the mechanical properties and electrochemical behavior of TiN and CrN single-layer and CrN/TiN multi-layer coatings deposited by PVD method on a dental alloy

Cited by 20 publications

References 36 publications

Comparing electrochemical behavior of applied CrN/TiN nanoscale multilayer and TiN single-layer coatings deposited by CAE-PVD method

Comparing electrochemical behavior of applied CrN/TiN nanoscale multilayer and TiN single-layer coatings deposited by CAE-PVD method

Electrochemical behavior of TiN, CrN and TiN/CrN nanostructured coatings on the nickel-chromium alloy used in dental fixed prosthesis

Synthesis of biocompatible coating on Ni-Cr alloy by cathodic cage plasma processing technique as anti-pathogenic bacteria for medicinal applications

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