In this study, novel Ag@MnO 2 nanowires were constructed by one step hydrothermal method, which exhibited excellent efficiency towards the photodegradation of organic contaminants under visible-light driven irradiation. The resulting Ag@MnO 2 nanowires were systematically characterized by various spectroscopic and microscopic techniques.Morphological characterizations show that the Ag nanoparticles are well anchored on the surface of the MnO 2 nanowires. The N 2 adsorption/desorption studies revealed that the as prepared photocatalyst possess mesoporosity. The optical properties and energy band gap structures were studied by UV-visible diffuse reflectance spectroscopy. The photocatalytic activity enhancement of Ag@MnO 2 (5%) nanowires could be ascribed to the efficient separation of photogenerated electron-hole pairs compared to other Ag@MnO 2 nanowires and pure MnO 2 . The possible photocatalytic mechanism was proposed for this enhanced charge separation performance using photoluminescence spectra analysis, electrochemical impedance spectroscopy (EIS) spectra and photocurrent density. Furthermore, photocatalytic mechanism investigations demonstrate that • OH and O 2 •− play a key role and h + plays a minor role in the photocatalytic process. We believe that our findings can open a new avenue for photocatalytic applications of Ag@MnO 2 nanowires.