“…Note in this context that the relevant rates of liquid-vapor isotopic exchange may depend upon, for example, properties of the geologic material (Hsieh et al, 1998b;Wassenaar et al, 2008), physicochemical states (Ingraham and Criss, 1998), and saturation controlled liquid surface area to volume ratio (Ingraham and Criss, 1993;Costanza-Robinson and Brusseau, 2002), with implications for the actual resolvability of dynamic liquid pore water signatures. In addition and similar to previous sampling approaches (e.g., Landon et al, 1999;FigueroaJohnson et al, 2007;Wassenaar et al, 2008), the process information may be blurred by unconsidered alteration of liquid soil water isotopic composition itself (e.g., due to interactions with inorganic or organic soil constituents) or unclear contribution of water stored in different compartments of the pore space (e.g., Brooks et al, 2010).…”