Compatibilization and toughening of co-continuous ternary blends via partially wet droplets at the interface

Zolali, Ali M.; Favis, Basil D.

doi:10.1016/j.polymer.2017.02.093

Cited by 57 publications

(63 citation statements)

References 56 publications

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“…Such an increase in complex viscosity, especially in low‐frequency regions, reflects the nanoparticles' interactions and the dispersion effect in the polymeric matrix . The highest increase in complex viscosity in the ternary systems occurred in the TiO 2 system [Figure (a)], possibly due to the TiO 2 selective localization at the interface, which enabled a compatibilization effect in that mixture …”

Section: Resultsmentioning

confidence: 99%

“…21,22 The highest increase in complex viscosity in the ternary systems occurred in the TiO 2 system [ Figure 5(a)], possibly due to the TiO 2 selective localization at the interface, 33 which enabled a compatibilization effect in that mixture. 5,7,41 In the hybrid of TiO 2 /hBN in the PCL/PLA mixture [ Figure 5 (a)], the complex viscosity presented higher values in a wide angular-frequency range than the ternary systems, with more evidence in the PCL/PLA/TiO 2 /hBN quaternary systems. Such higher increase in complex viscosity can be attributed to stronger TiO 2 /hBN interactions, which lead to a better hBN and…”

Section: Nanoparticle Selective Localizationmentioning

confidence: 99%

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Effects of processing conditions on hybrid filler selective localization, rheological, and thermal properties of poly(ε‐caprolactone)/poly(lactic acid) blends

Decol

Pachekoski

Segundo

et al. 2019

J of Applied Polymer Sci

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In this study, the effects of processing conditions through different mixing sequences were used to analyze the factors, which could influence the hybrid filler selective localization in an immiscible polymer blend and how localization can influence the rheological and thermal properties. Different selective localizations were observed depending on the mixing sequence used when the hybrid filler was added. Notably, nanoparticles can interact with each other, which favor a synergy between them and alters, besides the localization, the dispersion state, or can interact with one polymer phase, and also alter the nanoparticles' selective localization. An improvement in rheological properties was observed in the hybrid nanocomposite in which there was interaction between the nanoparticles, favoring the hexagonal boron nitride exfoliation. On the other hand, for the storage modulus and degree of crystallinity, the sharpest increase occurred in the hybrid nanocomposite in which the nanoparticles could interact preferably with one polymer phase. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 137, 48711.

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Section: Resultsmentioning

confidence: 99%

Section: Nanoparticle Selective Localizationmentioning

confidence: 99%

Effects of processing conditions on hybrid filler selective localization, rheological, and thermal properties of poly(ε‐caprolactone)/poly(lactic acid) blends

Decol

Pachekoski

Segundo

et al. 2019

J of Applied Polymer Sci

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“…HLNR sebagai pengserasi membantu dalam meningkatkan kelekatan antara fasa getah dan fasa polistirena. Daya tegangan antara muka dikurangkan dan interaksi antara fasa dalam matriks ditingkatkan oleh pengserasi (Zolali & Favis 2017). Taburan fasa yang homogen (Jose et al 2016) …”

Section: Sifat Mekanikunclassified

Sintesis dan Pencirian Getah Asli Cecair Terhidrogen untuk Adunan Polimer

Yusof

Abdullah

Yusoff³

2017

JSM

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“…The final properties of the ternary blends can be influenced by some important factors such as composition, viscosity ratio, compatibilizer type, and mixing conditions . Various researches have been trying to realize the correlation of affecting parameters with the morphology and final properties of this class of polymer blends . For example, Li et al employed different processing methods for preparation of the polyamide‐6 (PA‐6)/maleic anhydride–grafted ethylene propylene diene monomer (EPDM‐g‐MA)/high density poly ethylene (HDPE) ternary blends.…”

Section: Introductionmentioning

confidence: 99%

“…[5][6][7] Various researches have been trying to realize the correlation of affecting parameters with the morphology and final properties of this class of polymer blends. [8][9][10][11][12] For example, Li et al 13 employed different processing methods for preparation of the polyamide-6 (PA-6)/maleic anhydride-grafted ethylene propylene diene monomer (EPDM-g-MA)/high density poly ethylene (HDPE) ternary blends. They reported that a thicker EPDM-g-MA shell could be seen in the two-step mixing method in comparison with one-step procedure.…”

Section: Introductionmentioning

confidence: 99%

Does nanoclay addition always lead to amelioration? Dual effects of the nanoclay on the PA‐6/EVOH/SEBS ternary blends

Shabani

Babaei

Zanjanijam

2019

Polymers for Advanced Techs

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This work presents the investigation of properties of polyamide‐6 (PA‐6)/ethylene vinyl alcohol (EVOH)/styrene‐ethylene‐butylene‐styrene (SEBS) ternary blends and related nanocomposites with nanoclays. In this way, the effect of the mixing protocol and nanoclay type on the morphology, mechanical, and rheological properties of the blends was comprehensively studied. Scanning electron microscopy (SEM) observation revealed that, for the neat ternary blends, core‐shell droplets were formed in which SEBS droplets were encapsulated by EVOH phase in the PA‐6 matrix. In this regard, experimental observations were compared and discussed with the predictions of phenomenological models. According to the X‐ray diffraction analysis, the distribution and degree of dispersion of the nanoclays were significantly influenced by mixing protocol. It was demonstrated that competition between the intrinsic effect of the nanoclay on the physical properties and its inhibiting effect on the interactions between PA‐6 and EVOH phases led to some interesting observations for the rheological and mechanical properties of the ternary blends. The results revealed that optimum properties could be obtained by selecting appropriate nanoclay and mixing protocol.

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Compatibilization and toughening of co-continuous ternary blends via partially wet droplets at the interface

Cited by 57 publications

References 56 publications

Effects of processing conditions on hybrid filler selective localization, rheological, and thermal properties of poly(ε‐caprolactone)/poly(lactic acid) blends

Effects of processing conditions on hybrid filler selective localization, rheological, and thermal properties of poly(ε‐caprolactone)/poly(lactic acid) blends

Sintesis dan Pencirian Getah Asli Cecair Terhidrogen untuk Adunan Polimer

Does nanoclay addition always lead to amelioration? Dual effects of the nanoclay on the PA‐6/EVOH/SEBS ternary blends

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