Competing magnetic interactions and magnetocaloric effect in Ho$_5$Sn$_3$

Abstract

The rare-earth intermetallic compound Ho5Sn3 demonstrates fascinating magnetic properties which include temperature driven multiple magnetic transitions and field driven metamagnetism. We address the magnetic character of this exciting compound through a combined experimental and theoretical studies. Ho5Sn3 orders antiferromagnetically below 28 K, and shows further spin reorientation transitions at 15 K and 12 K. We observe a sizable amount of low-temperature magnetocaloric effect in Ho5Sn3 with a maximum value of entropy change ∆S = -9.5 JKg −1 K −1 for an applied field of H = 50 kOe at around 30 K. The field hysteresis is almost zero above 15 K where magneto-caloric effect is important. Interestingly, ∆S is found to change its sign from positive to negative as the temperature is increased above about 8 K, which can be linked to the multiple spin reorientation transitions. The signature of the metamagnetism is visible in the ∆S versus H plot. The magnetic ground-state, obtained from the density functional theory based calculation, is susceptible to the effective Coulomb interaction (U eff ) between electrons. Depending upon the value of U eff , the ground-state can be ferromagnetic or antiferromagnetic. The compound shows large relaxation (14% change in magnetization in 60 min) in the field cooled state with a logarithmic time variation, which may be connected to the competing magnetic ground-states observed in our theoretical calculations. The competing magnetic ground-states is equally evident from the small value of the paramagnetic Curie-Weiss temperature.