Competitive Detection of Volatile Compounds from Food Degradation by a Zinc Oxide Sensor

Abstract

During the phenomenon of food degradation, several volatile organic compounds are generally released. In particular, due to lipid oxidation in stored and packed meat, hexanal is formed as a typical decomposition product. Therefore, its detection can provide an important indication of the quality and conservation of meat. Unfortunately, the simultaneous release of other compounds, such as 1-pentanol and 1-octen-3-ol, during the first phase of the degradation process can have an undesirable effect on the detection of hexanal. In this work, a metal oxide (MOX) sensor based on zinc oxide (ZnO) was prepared and tested for possible use in the monitoring of low concentrations of hexanal. The sensor was expected to detect the target volatile with minimum interference from all the others, when released all at the same time. For this purpose, the ZnO sensor was exposed to both pure and different mixtures of vapors of the main competing organic compounds. Comparing the results of the mixtures to the response relating to pure hexanal, it was highlighted that the presence of 1-pentanol and 1-octen-3-ol decreases the response of the sensor to hexanal in terms of the eR/R0 ratio, especially at low concentrations (5–10 ppm), while at 50 ppm, the sensor response was comparable with the hexanal quantity, proving that its detection was less affected at higher concentrations.

A Portable Device for I–V and Arrhenius Plots to Characterize Chemoresistive Gas Sensors: Test on SnO2-Based Sensors

“…Metal-oxide (MOX) gas sensors, thanks to their high sensitivity (attaining a detection limit up to tens of ppb) [ 1 , 2 , 3 , 4 ], low power consumption, fast response (within 10–20 min), and recovering time (typically 15–30 min) [ 4 , 5 ], are widely used in different application fields, such as environmental [ 6 , 7 , 8 ], industrial [ 9 ], agri-food [ 10 , 11 , 12 , 13 , 14 ], medical [ 15 , 16 , 17 , 18 , 19 , 20 , 21 ], etc. MOX sensor sensing principle is based on chemoresistivity (i.e., their electrical resistance changes as a function of the chemical reactions between the surface and a gaseous analyte), which is enhanced by nanostructured manufacturing the sensing film (i.e., the film is made up of an interconnected network of semiconductor nanograins).…”