Let L m,n denote the convex set of completely positive trace preserving operators from C m×m to C n×n , i.e quantum channels. We give a necessary condition for L ∈ L m,n to be an extreme point. We show that generically, this condition is also sufficient. We characterize completely the extreme points of L 2,2 and L 3,2 , i.e. quantum channels from qubits to qubits and from qutrits to qubits.2010 Mathematics Subject Classification. 15B48, 47B65, 94A17, 94A40