Complex metal halides in fused alkali nitrates

Kinetics of reactions involving bromate in fused alkali nitrates

“…Iverson (9) and Yaniamoto (10) The metal chlorates were found to decompose slowly to form Clg and 01 , with the latter being the major product. Table 8, which illustrates this (23)(24)(25)(26).…”

Acid-base reactions and kinetics of the halates in fused nitrates

“…The results are very close to those obtained in sodium and potassium nitrate solvent. Iverson (8) has shown that other ions present in the melt have little effect on the solubility of barium chromate. Therefore the equilibrium constants for all the reactions were evaluated using the solubility obtained in sodium-potassium nitrate mixtures.…”

“…Only re cently have reactions been conducted in fused electrolytes using tne fused salt as a solvent. Yamamoto (8) observed the reaction between nitrate and dichromate when studying lead chloride complexes in a eutectic mixture of sodium and potassium nitrate. Upon adding chloride and bromide and varying the concentration of lead nitrate, he concluded that the following equilibrium existed in fused nitrates:…”

“…Solubilities of barium chromate et several tempera tures in mixtures of sodium and potassium nitrate8 …”

Complex ions in fused salts

“…Iverson (48) determined the values of K% given in Table 12 by determining the solubility product of CdCrO^ in the fused eutectlc solvent and then investigating the increase in solubility of the cadmium salt on the addition of alkali bromide. This increase in solubility was attributed to complex should be much more precise than measurement by the solubility product method.…”