Complex of Copper(II) with Ethylenediamine and Decyl Sulfate Ions. Formation in Water and Crystal Structure

Diaquabis(propane-1,2-diamine-κ2N,N′)copper(II) terephthalate dihydrate

“…In similar complexes, the Cu-N bond lengths lie in the range 2.00-2.05 Å (Li et al, 1999;Procter et al, 1968). The Cu-O1W distance of 2.377 (2) Å is consistent with other copper(II) complexes with water (Amirov et al, 2003), but the Cu-O2W distance of 2.895 (3) Å is longer than the normal value and indicates weak coordination. N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen bonds (Fig.…”

Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-fluorobenzoate)

“…In similar complexes, the CuÐN bond lengths lie in the range 2.00±2.05 A Ê (Li et al, 1999;Procter et al, 1968). The CuÐO water distance of 2.579 (4) A Ê is appreciably longer than for other copper(II) complexes with water (Amirov et al, 2003).…”

Design of High-Relaxivity Polyelectrolyte Nanocapsules Based on Citrate Complexes of Gadolinium(III) of Unusual Composition

“…Features of the mechanism of proton relaxation in gadolinium solutions (an increase in the relaxivity due to the slow-down of rotation of Gd(III) ions bound to nanoparticle) revealed not only aggregation in the solutions of surfactants [22,23] or lipophilic macrocycles [24,25], but also the binding of cations with polymers [26], or graphene oxide [27,28]. In addition, the authors of this current paper have previously discovered that metal ion complexes can form associates with oppositely charged ions of surfactants, macrocycles, or polymers [29][30][31][32].…”