“…The final stage of thermolysis of compounds 1 , 3 , and 4 is characterized by powerful endothermic effects similar in form and intensity that correspond to the decomposition and subsequent desorption of the organic part of the complexes. 59–61 A correlation between the extrema of the endo-effects and the structural organization of the complex is observed: 381 °C (3) > 365 °C (1) 357 °C (2). (Compound 3 contains no coordinated solvent molecules, whereas 4 contains not only coordinated but also outer-sphere water molecules that reduce the overall complex stability).…”
Four new frameworks were obtained by slow diffusion of a ligand solution - 1,2-bis(4-pyridyl)ethylene (dpe) into solutions of NiII and CoII furoates. It is shown that, depending on the combination...
“…The final stage of thermolysis of compounds 1 , 3 , and 4 is characterized by powerful endothermic effects similar in form and intensity that correspond to the decomposition and subsequent desorption of the organic part of the complexes. 59–61 A correlation between the extrema of the endo-effects and the structural organization of the complex is observed: 381 °C (3) > 365 °C (1) 357 °C (2). (Compound 3 contains no coordinated solvent molecules, whereas 4 contains not only coordinated but also outer-sphere water molecules that reduce the overall complex stability).…”
Four new frameworks were obtained by slow diffusion of a ligand solution - 1,2-bis(4-pyridyl)ethylene (dpe) into solutions of NiII and CoII furoates. It is shown that, depending on the combination...
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