Complexing agent engineered strategy for anchoring SnO2 nanoparticles on sulfur/nitrogen co-doped graphene for superior lithium and sodium ion storage

Wang, Heng‐guo; Jiang, Cheng; Yuan, Chenpei; Wu, Qiong; Li, Qiang; Duan, Qian

doi:10.1016/j.cej.2017.09.081

Cited by 57 publications

(29 citation statements)

References 54 publications

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“…The N 1 s spectrum in Fig. 3 e contains three main peaks at 398.2, 400.5, and 406.3 eV, which is associated with the pyridinic, pyrrolic, and graphitic types of N atoms, respectively [ 35 , 46 ]. In the high-resolution S 2 p spectrum (Fig.…”

Section: Resultsmentioning

confidence: 99%

Flexible Conductive Anodes Based on 3D Hierarchical Sn/NS-CNFs@rGO Network for Sodium-Ion Batteries

Luo

Song

et al. 2019

Nano-Micro Lett.

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HIGHLIGHTS • 3D hierarchical conductive Sn quantum dots encapsulated in N,S co-doped carbon nanofibers sheathed within rGO scrolls (Sn/NS-CNFs@rGO) were prepared through an electrospinning process. • Flexible Sn/NS-CNFs@rGO electrode exhibits superior long-term cycling stability and high-rate capability in sodium-ion batteries. ABSTRACT Metallic Sn has provoked tremendous progress as an anode material for sodium-ion batteries (SIBs). However, Sn anodes suffer from a dramatic capacity fading, owing to pulverization induced by drastic volume expansion during cycling. Herein, a flexible three-dimensional (3D) hierarchical conductive network electrode is designed by constructing Sn quantum dots (QDs) encapsulated in one-dimensional N,S codoped carbon nanofibers (NS-CNFs) sheathed within two-dimensional (2D) reduced graphene oxide (rGO) scrolls. In this ingenious strategy, 1D NS-CNFs are regarded as building blocks to prevent the aggregation and pulverization of Sn QDs during sodiation/desodiation, 2D rGO acts as electrical roads and "bridges" among NS-CNFs to improve the conductivity of the electrode and enlarge the contact area with electrolyte. Because of the unique structural merits, the flexible 3D hierarchical conductive network was directly used as binder-and current collectorfree anode for SIBs, exhibiting ultra-long cycling life (373 mAh g −1 after 5000 cycles at 1 A g −1), and excellent high-rate capability (189 mAh g −1 at 10 A g −1). This work provides a facile and efficient engineering method to construct 3D hierarchical conductive electrodes for other flexible energy storage devices.

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Section: Resultsmentioning

confidence: 99%

Flexible Conductive Anodes Based on 3D Hierarchical Sn/NS-CNFs@rGO Network for Sodium-Ion Batteries

Luo

Song

et al. 2019

Nano-Micro Lett.

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“…The limited storage performance of graphite cannot satisfy the eager requirements for high energy/power density devices. Simultaneously, the research on SIBs has gained sufficient momentum owing to their similar electrochemical mechanisms to LIBs and abundant sodium reserves. , Unfortunately, the higher reduction potential ( E Na/Na + = −2.7 V vs E Li/Li + = −3.0 V) and the larger radius (1.02 Å for Na vs 0.76 Å for Li) usually result in the low energy density and poor cycle stability in SIBs . The graphite presents nearly no capacity for SIBs.…”

Section: Introductionmentioning

confidence: 99%

Binary-Metal Mn₂SnO₄ Nanoparticles and Sn Confined in a Cubic Frame with N-Doped Carbon for Enhanced Lithium and Sodium Storage

Wan

Liu

Cheng

et al. 2021

ACS Appl. Mater. Interfaces

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Sn-based materials have been popularly researched as anodes for energy storage due to their high theoretical capacity. However, the sluggish reaction kinetics and unsatisfied cycling stability caused by poor conductivity and dramatic volume expansion are still pivotal barriers for the development of Sn-based materials as anodes. In this work, the binary-metal Mn2SnO4 nanoparticles and Sn encapsulated in N-doped carbon (Sn@Mn2SnO4-NC) were fabricated by multistep reactions and employed as the anode for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). The coexistence of binary metals (Sn and Mn) can improve intrinsic conductivity. Simultaneously, hollow architecture along with carbon relieves internal stress and prevents structural collapse. A Sn@Mn2SnO4-NC anode delivers an appealing capacity of 1039.5 mAh g–1 for 100 cycles at 100 mA g–1 and 823.8 mAh g–1 for 600 cycles at 1000 mA g–1 in LIBs. When evaluated as an anode in SIBs, the Sn@Mn2SnO4-NC anode tolerates up to 7000 cycles at 2000 mA g–1 and maintains a capacity of 185.8 mAh g–1. Quantified kinetic investigations demonstrate the high contribution of pseudocapacitive effects during the cycle process. Furthermore, density functional theory (DFT) calculations further verify that introduction of the second metal (Mn) improves the conductivity of the material, which is favorable for charge transport. This work is expected to provide a feasible preparation strategy for binary-metal materials to enhance the performance of lithium- and sodium-ion batteries.

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“…Numerous nanostructured metal oxides of diverse morphologies, such as manganese oxide (MnO 2 ), , cobalt oxide (Co 3 O 4 ), tungsten dioxide (WO 2 ), titania (TiO 2 ), , silica (SiO 2 ), tin oxide (SnO 2 ), cupric/cuprous oxide CuO/Cu 2 O, , etc. have been probed as anode materials for application in LIBs.…”

Section: Introductionmentioning

confidence: 99%

“…10 However, further improvement in power density, cycle stability, charging−discharging rate, and safety concern associated with electrode materials remained as significant challenges for a breakthrough in LIBs. 11 Numerous nanostructured metal oxides of diverse morphologies, such as manganese oxide (MnO 2 ), 12,13 cobalt oxide (Co 3 O 4 ), 14 tungsten dioxide (WO 2 ), 15 titania (TiO 2 ), 16,17 silica (SiO 2 ), 18 tin oxide (SnO 2 ), 19 cupric/cuprous oxide CuO/Cu 2 O, 20,21 etc. have been probed as anode materials for application in LIBs.…”

Section: ■ Introductionmentioning

confidence: 99%

Piper longum Extract-Mediated Green Synthesis of Porous Cu₂O:Mo Microspheres and Their Superior Performance as Active Anode Material in Lithium-Ion Batteries

Kumar

Al-Muhtaseb

Kumar

et al. 2020

ACS Sustainable Chem. Eng.

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Fabrication of nano-and microstructure-based anodes capable of accommodating the lithiation-induced strain, high specific capacity, and longer cycling stability is the principal challenge for developing next-generation lithium-ion batteries (LIBs) with higher energy density. Herein, we report a green route for fabricating porous molybdenum-doped cuprous oxide (Cu 2 O:Mo) microspheres of high specific surface area. The porous Cu 2 O:Mo microspheres have been utilized as active anode materials in LIBs, revealing excellent electrochemical performance. The electrodes fabricated with the porous Cu 2 O:Mo microspheres yielded outstanding Li-ion uptake performance, with a specific capacity of 1128 mAh g −1 at 0.1 Ag −1 and enhanced rate performance, and cycling stability (1082 mAh g −1 at 0.1 Ag −1 after 100 charge−discharge cycles). Enhanced specific capacity, stable cycling stability, and excellent rate capability of the fabricated electrodes indicate the porous Cu 2 O:Mo microspheres are potential anode material for fabricating next-generation high-performance LIBs. The synthetic approach adapted for fabricating the porous Cu 2 O:Mo microspheres is facile, relatively greener, and low-cost, which can be utilized for fabricating other metal oxide-based porous microstructures for application in energy storage devices.

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Complexing agent engineered strategy for anchoring SnO2 nanoparticles on sulfur/nitrogen co-doped graphene for superior lithium and sodium ion storage

Cited by 57 publications

References 54 publications

Flexible Conductive Anodes Based on 3D Hierarchical Sn/NS-CNFs@rGO Network for Sodium-Ion Batteries

Flexible Conductive Anodes Based on 3D Hierarchical Sn/NS-CNFs@rGO Network for Sodium-Ion Batteries

Binary-Metal Mn₂SnO₄ Nanoparticles and Sn Confined in a Cubic Frame with N-Doped Carbon for Enhanced Lithium and Sodium Storage

Piper longum Extract-Mediated Green Synthesis of Porous Cu₂O:Mo Microspheres and Their Superior Performance as Active Anode Material in Lithium-Ion Batteries

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Complexing agent engineered strategy for anchoring SnO2 nanoparticles on sulfur/nitrogen co-doped graphene for superior lithium and sodium ion storage

Cited by 57 publications

References 54 publications

Flexible Conductive Anodes Based on 3D Hierarchical Sn/NS-CNFs@rGO Network for Sodium-Ion Batteries

Flexible Conductive Anodes Based on 3D Hierarchical Sn/NS-CNFs@rGO Network for Sodium-Ion Batteries

Binary-Metal Mn2SnO4 Nanoparticles and Sn Confined in a Cubic Frame with N-Doped Carbon for Enhanced Lithium and Sodium Storage

Piper longum Extract-Mediated Green Synthesis of Porous Cu2O:Mo Microspheres and Their Superior Performance as Active Anode Material in Lithium-Ion Batteries

Contact Info

Product

Resources

About

Binary-Metal Mn₂SnO₄ Nanoparticles and Sn Confined in a Cubic Frame with N-Doped Carbon for Enhanced Lithium and Sodium Storage

Piper longum Extract-Mediated Green Synthesis of Porous Cu₂O:Mo Microspheres and Their Superior Performance as Active Anode Material in Lithium-Ion Batteries