Post-anesthesia recovery is a vital phase in the perioperative continuum, where the quality of care and monitoring heavily influence patient outcomes. This comprehensive review examines the Sampe, Modified Aldrete, and White Scoring Systems, pivotal in evaluating patients' readiness for discharge from the Post-Anesthesia Care Unit (PACU). The review delves into the historical evolution of post-anesthesia care, highlighting the transition from minimal post-operative support to the establishment of PACUs and the subsequent development of structured recovery scoring systems. Each scoring system is analyzed in detail, focusing on its components, criteria, scoring methodology, advantages, and limitations. A comparative analysis underscores these systems' similarities and differences, sensitivity, specificity, and practical applications in clinical settings. Additionally, the review discusses the clinical implications of these scoring systems in enhancing patient management, improving safety, and ensuring standardized care. Emerging technologies and future directions in recovery assessment are also explored, providing insights into potential innovations. This review aims to equip healthcare professionals with a deeper understanding of these scoring systems, facilitating informed decisions to optimize post-anesthesia care and patient outcomes.