Components of the Shear Modulus and Their Dependence on Temperature and Plastic Deformation of a Metallic Glass

Abstract

High-precision measurements of the temperature dependences of the high-frequency shear modulus G performed on as-cast, preannealed and predeformed Zr46Cu45Al7Ti2 bulk metallic glass allowed us to determine, for the first time, the harmonic, anharmonic, electronic and relaxation components of G. The dependence of anharmonic, electronic and relaxation components on temperature and preliminary inhomogeneous (localized) plastic deformation was investigated. It is found that plastic deformation results in a significant change in these components. We showed that the increase in the integral relaxation contribution to the shear modulus with an increase in plastic deformation can be quantitatively described within the framework of the interstitialcy theory. It is also found that plastic deformation simultaneously leads to an increase in the anharmonic and decrease in the electronic components of the shear modulus.

On the Nature of the Excess Internal Energy and Entropy of Metallic Glasses

“…Ref. [21]). At that, the derivative dξ sql /d∆S rt , accounting for the scatter, is about the same for initial/relaxed/tellurite glasses.…”