“…Currently, lithium-ion batteries (LIBs) are still dominating the energy storage application for not only the consumer electronics market, − but also the electric vehicles (EVs) market. , However, it is still important to increase the long-distance transportation capability of EVs to further expand their market share. − Thus, the use of a battery system with enhanced energy density is critical to achieving this mission. − Due to the ultrahigh capacity and low weight of lithium metal anode, the theoretical volumetric energy density of lithium metal batteries (LMBs) can reach 1200 Wh/L compared to only 500 Wh/L in LIBs. , However, the practical application of LMB was still hindered by its limited battery life and severe safety concerns. − Therefore, the construction of a stable interphase between lithium metal and electrolyte is essential to realize the long-term cycling of LMBs. − Many innovative methods such as artificial interphases on the lithium anode, − all solid-state electrolytes, − concentrated electrolytes, − and localized concentrated electrolytes, − have been proposed to elongate the battery life and enhance the safety of the LMBs. Among all these proposals, the use of electrolyte additives is the most cost-effective approach since it only requires the mixing of additive materials into the electrolyte before injection into the cell.…”