The quest for novel kinetic promoters
for efficient storage and
safe transportation of natural gas in the form of hydrates is an ongoing
endeavor. In this study, the kinetics of methane hydrate formation
have been investigated in the presence of low-foaming, nonionic, 1-dodecyl-2-pyrrolidinone
and tetrahydrofuran in aqueous solution in a stirred tank reactor.
The first phase of experiments has been conducted at 5 MPa and 274.15
K with varying concentrations of 1-dodecyl-2-pyrrolidinone (0.1, 0.5,
1, and 2 wt %). Similarly, the second phase of experiments has been
conducted with two different concentrations of THF (19.49 and 3.89
wt %) along with 0.5 and 2 wt % of 1-dodecyl-2-pyrrolidinone using
methane gas as the hydrate former at 5 MPa and 282.55 K. The pressure
and temperature conditions are chosen covering both sI and sII regions.
Information on the number of moles of gas consumed during hydrate
formation, induction time, water-to-hydrate/gas-to-hydrate conversion,
and gas storage capacity are investigated. It is observed that 1-dodecyl-2-pyrrolidinone
shows good hydrate promotion characteristics with pure water for all
the selected concentrations, with 0.5 wt % being on the higher side.
Also, it has been observed that 1-dodecyl-2-pyrrolidinone serves as
an effective kinetic promoter for the mixed methane–tetrahydrofuran
hydrate at a moderate pressure and temperature of 5 MPa and 282.55
K. This study will assist in storing multifold volumes of natural
gas in compact hydrate crystals suitable for natural gas storage and
transportation applications.