Compressed composite carbon felt as a negative electrode for a zinc–iron flow battery

Abstract

Flow batteries possess several attractive features including long cycle life, flexible design, ease of scaling up, and high safety. They are considered an excellent choice for large-scale energy storage. Carbon felt (CF) electrodes are commonly used as porous electrodes in flow batteries. In vanadium flow batteries, both active materials and discharge products are in a liquid phase, thus leaving no trace on the electrode surface. However, zinc-based flow batteries involve zinc deposition/dissolution, structure and configuration of the electrode significantly determine stability and performance of the battery. Herein, fabrication of a compressed composite using CF with polyvinylidene fluoride (PVDF) is investigated in a Zn–Fe flow battery (ZFB). Graphene (G) is successfully introduced in order to improve its electrochemical activity towards zinc reactions on the negative side of the ZFB. A compressed composite CF electrode offers more uniform electric field and lower nucleation overpotential (NOP) of zinc than a pristine CF, resulting in higher zinc plating/stripping efficiency. Batteries with modified electrodes are seen to provide lower overpotential. Particularly, the G-PVDF-CF electrode demonstrates maximum discharge capacity of 39.6 mAh cm−2 with coulombic efficiency and energy efficiency over 96% and 61%, respectively. Finally, results lead to increased efficiency and cycling stability for flow batteries.

Extending the lifetime of vanadium redox flow batteries by reactivation of carbon electrode materials

“…From the slope of the peak currents, the double-layer capacitance ( C dl ) of the electrodes can be obtained, which together with the specific capacitance ( C sp ) is used to obtain the ECSA. 27 The calculation and results for the ECSA are shown in the ESI Fig. S2–10 †.…”

Porous Graphite Felt Modified with Carbon Nanoparticles for an MV/4-HO-TEMPO Flow Battery

“…The single cell achieved a 6% increase in efficiency at 100 mA/cm 2 , but it showed relatively poor long-term cycling stability. Saupsor et al soaked carbon fibers (CF) in a PVDF solution containing graphene to prepare composite electrodes for zinc–iron flow batteries (ZFB). Although they achieved more uniform zinc deposition on the surface, the stability in long-term cycling tests was poor and the energy efficiency at high current densities lost its advantage.…”