2023
DOI: 10.1021/acs.langmuir.3c01648
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Compression and Ordering of Hollow Microgels in Monolayers Formed at Liquid–Liquid Interfaces

Nikita V. Bushuev,
Rustam A. Gumerov,
Andrey A. Rudov
et al.

Abstract: Monolayers of polymer microgels with a spherical cavity adsorbed at the liquid−liquid interface were studied using mesoscopic computer simulations. One liquid, named water, was always considered as a good solvent, while the microgel solubility in the second liquid, named oil, was varied. The symmetric and asymmetric cases of vanishing and the strong differences in solubility between the network particles and the liquids were considered. The simulations provided us with an insight into the shape and volume chan… Show more

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