Photovoltaic (PV)-integrated flow cells for electrochemical energy conversion and storage underwent a huge development. The advantages of this type of integrated flow cell system include the simultaneous storage of solar energy into chemicals that can be readily utilised for generating electricity. However, most studies overlook the practical challenges arising from the inherent heat exposure and consequent overheating of the reactor under the sun. This work aims at the prediction of the temperature profile across the PV-integrated electrochemical flow cell under light exposure conditions by introducing a computational fluid dynamics (CFD) method. Furthermore, we discuss the impact of the flow channel block architecture on the temperature profile to provide insights and guidelines for the effective remedy of overheating.