Low-voltage circuit breakers provide essential protection for industrial and residential power installations, by taking advantage of the voltage drop at the electrode–plasma interface to force current zero. This is accomplished by using the magnetic force and unbalanced pressure on the arc as the contacts open to push the arc toward a stack of steel plates that break the arc into subarcs and thereby multiply the number of voltage drops. As the fault current can be high, substantial energy can be dissipated, which results in interactions among the arc and solid counterparts in terms of wall ablation and metal evaporation. In this study, ablation experiments are conducted to demonstrate its great influence on the arc voltage and on the pressure field. Significant progress has been accomplished in the computation of arc dynamics through the coupling of fluid motion with electromagnetics, although an important mechanism in arc breaking simulation, the effect of Stefan flow caused by species generation, has not been considered. We report out a numerical approach for taking into account the effect of Stefan flow, particularly for the breakers with high gasifying wall materials. This approach accounts for the diffusion induced convection due to added-in species from the evaporation surfaces, which will largely influence the flow field and the properties of the plasma mixture. Apart from the voltage drop, this mechanism plays an important role in simulating arc interruption. The ability of conducting Stefan flow computation further enhances the understanding of arc behaviors and improves the design of practically oriented low-voltage circuit breakers.