As a main apparatus, the oxygen lance is used to deliver the oxygen element and transfer kinetic energy into the molten bath in the steelmaking process. However, the Laval nozzle exit would be gradually worn out during the service life, which suppresses the performance of the oxygen lance. This paper investigated three different wear length (Lw) conditions at the exit of the Laval nozzle through numerical simulations and high-temperature experiments with various oxygen flow rates. The result showed that the entrainment of the ambient gas was the key factor of the wear phenomenon for the Laval nozzle exit. The maximum total temperature of the gas phase at the Laval nozzle exit formed by the Lw of 0 mm, 2 mm, and 4 mm were 300 K, 959 K, and 1700 K, respectively. Thus, by increasing the Lw value, the total temperature of the gas phase was rapidly improved at the exit of the Laval nozzle, which further accelerated the wear phenomenon at the exit of the Laval nozzle. Besides, axial velocities at the end of the potential core formed by the Lw of 0 mm, 2 mm, and 4 mm were 483.7 m/s, 480.0 m/s, and 478.7 m/s, respectively. As a result, the wear phenomenon reduced the impaction ability of the oxygen jet, which suppressed the impaction depth and radius, resulting in a smaller droplet generation rate.