2023
DOI: 10.1021/acsorginorgau.3c00014
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Computational Study into the Effects of Countercations on the [P8W48O184]40– Polyoxometalate Wheel

Abstract: Porous metal oxide materials have been obtained from a ring-shaped macrocyclic polyoxometalate (POM) structural building unit, [P 8 W 48 O 184 ] 40− . This is a tungsten oxide building block with an integrated "pore" of 1 nm in diameter, which, when connected with transition metal linkers, can assemble frameworks across a range of dimensions and which are generally referred to as POMzites. Our investigation proposes to gain a better understanding into the basic chemistry of this POM, specifically local electro… Show more

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