Abstract:The present work is intended to bring to the forefront a relatively less
explored area of N-Heterocyclic Carbene (NHC) catalyzed alkyne hydro-
thiolation and selenation reactions. The present work can be regarded as
the first ever computational investigation on the catalytic activity of
the NHC catalyzed hydro- thiolation and selenation reactions by
exploring the reaction mechanism. Reaction mechanism involves
chalcogenol activation followed by alkyne insertion and the second step
is found to be the rate deter… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.