Diffractive optics have increasingly caught the attention of the scientific community. Classical diffractive optics are 2D diffractive optical elements (DOEs) and computer-generated holograms (CGHs), which modulate optical waves on a solitary transverse plane. However, potential capabilities are missed by the inherent two-dimensional nature of these devices. Previous work has demonstrated that extending the modulation from planar (2D) to volumetric (3D) enables new functionalities, such as generating space-variant functions, multiplexing in the spatial or spectral domain, or enhancing information capacity. Unfortunately, despite significant progress fueled by recent interest in metasurface diffraction, 3D diffractive optics still remains relatively unexplored. Here, we introduce the concept of azimuthal multiplexing. We propose, design, and demonstrate 3D diffractive optics showing this multiplexing effect. According to this new phenomenon, multiple pages of information are encoded and can be read out across independent channels by rotating one or more diffractive layers with respect to the others. We implement the concept with multilayer diffractive optical elements. An iterative projection optimization algorithm helps solve the inverse design problem. The experimental realization using photolithographically fabricated multilevel phase layers demonstrates the predicted performance. We discuss the limitations and potential of azimuthal multiplexing 3D diffractive optics.With feature sizes comparable to electromagnetic wavelength, diffractive optics offers a unique pathway to light manipulation 1-3 . It expands the capabilities of conventional optics based on refraction or reflection and in conjunction with free-form 4,5 , graded index 6 , and artificial (meta) materials 7,8 provide full access to the spatial degrees of freedom of light. Further, new insight in wave manipulation and the ever-increasing power of computers enable diffractive optics to generate user-defined wavefronts from arbitrary inputs, by virtue of degrees of freedom from pixels that can be addressed individually and independently 9-11 . Beyond classical applications such as beam shaping 12,13 , 3D display 14,15 , information security 16,17 , spectroscopy 18 , metrology 19 , and astronomical imaging 20 , emerging areas include optical tweezers 21,22 , novel microscopies 23,24 , coherent control 25,26 , quantum information 27,28 , neural networks 29,30 , and optogenetics 31,32 .Three dimensional (3D) diffractive optics expand the capabilities of traditional two-dimensional elements not only by providing higher diffraction efficiency and higher information capacity, but also enabling functionalities such as multiplexing and space-variant functions [33][34][35] . The capability of controlling multidimensional spatial, spectral, temporal, and coherence functions of light fields is originated from the multi-subject nature of 3D diffractive optics involving diffraction, refraction, absorption, resonances, and scattering.In spite of being a topic of gr...