Concentration effect of Sm3+ ions in B2O3–PbO–PbF2–Bi2O3–ZnO glasses – Structural and luminescence investigations

Arunkumar, S.; Marimuthu, K.

doi:10.1016/j.jallcom.2013.02.151

Cited by 154 publications

(49 citation statements)

References 30 publications

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“…For BTNA:Sm 3+ samples, the β exp values of 4 G 5/2 → 6 H 7/2 transition are 53.5, 54.6 and 53.2 % for concentrations of 0.1, 0.5 and 1.0 mol% Sm 3+ , respectively. These values are comparable to those in literature [5,[6][7][8]. Thus, the 4 G 5/2 → 6 H 7/2 transition of Sm 3+ in BTNA glasses has a promising potential for optical applications.…”

Section: Optical Parameters Of Sm 3+ Ion In Btna:sm 3+ Glassessupporting

confidence: 89%

“…Ω 4 /Ω 6 ratio (χ) is called as the spectroscopic quality factor that it is important to characterize the quality of optical materials [5]. The values of χ in BTNA:Sm 3+ is large and comparable to the Sm 3+ -doped other hosts [6][7][8]. This suggests that the BTNA:Sm 3+ crystal is a good optical material.…”

Section: Optical Parameters Of Sm 3+ Ion In Btna:sm 3+ Glassesmentioning

confidence: 99%

“…Therefore, the absorption transitions are overlapped and that creates broad bands. The strongest intensity in this region corresponds to 6 H 5/2 → 6 P 3/2 transition (at the wavelength of 402 nm). This transition is a spin allowed transition which is normally used for fluorescence excitation.…”

mentioning

confidence: 96%

“…Spectral properties of rare earth ions in glasses vary in a wide range depending on the chemical composition of glass former and modifier [3,4]. Among lanthanides, the Sm 3+ ion is one of the most interesting ions for analyzing the fluorescence properties because it is widely used in the fields such as undersea communications, high-density memories, colour displays and solid-state laser [2,[5][6][7][8].…”

mentioning

confidence: 99%

“…Borate glasses have been extensively investigated due to intriguing properties such as good transparency in the infrared, low melting point, high solubility of rare earth [2][3][4]8]. The disadvantage of these glasses is that high phonon energy (around 1300-1500 cm -1 ) results in strong occurrence of multi-phonon and reduces the luminescence efficiency of the material [3,4,6,7]. The phonon energy of TeO 2 is about 750 cm -1 [4].…”

mentioning

confidence: 99%

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Sm3+ Doped Borotellurite Glass: Absorption, Fluorescence and Optical Parameters

Độ¹

2018

MaP

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Borotellurite glasses doped with Sm 3+ ions were prepared by a melt-quenching technique. The studies on optical characterization of Sm 3+ ions have been carried out through absorption, emission and decay spectra. Judd-Ofelt (JO) intensity analysis has been presented and JO parameters were calculated for Sm 3+ ions in borotellurite glasses. Radiative properties such as transition probabilities, branching ratios, radiative lifetime of 4 G 5/2 level and quantum efficiency were estimated by using JO parameters.

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Section: Optical Parameters Of Sm 3+ Ion In Btna:sm 3+ Glassessupporting

confidence: 89%

Section: Optical Parameters Of Sm 3+ Ion In Btna:sm 3+ Glassesmentioning

confidence: 99%

mentioning

confidence: 96%

mentioning

confidence: 99%

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confidence: 99%

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Sm3+ Doped Borotellurite Glass: Absorption, Fluorescence and Optical Parameters

Độ¹

2018

MaP

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Halide Double Perovskite Nanocrystals Doped with Rare‐Earth Ions for Multifunctional Applications

Wang

Jiang

et al. 2023

Advanced Science

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Most lead-free halide double perovskite materials display low photoluminescence quantum yield (PLQY) due to the indirect bandgap or forbidden transition. Doping is an effective strategy to tailor the optical properties of materials. Herein, efficient blue-emitting Sb 3+ -doped Cs 2 NaInCl 6 nanocrystals (NCs) are selected as host, rare-earth (RE) ions (Sm 3+ , Eu 3+ , Tb 3+ , and Dy 3+ ) are incorporated into the host, and excellent PLQY of 80.1% is obtained. Femtosecond transient absorption measurement found that RE ions not only served as the activator ions but also filled the deep vacancy defects. Anti-counterfeiting, optical thermometry, and white-light-emitting diodes (WLEDs) are exhibited using these RE ions-doped halide double perovskite NCs. For the optical thermometry based on Sm 3+ -doped Cs 2 NaInCl 6 :Sb 3+ NCs, the maximum relative sensitivity is 0.753% K −1 , which is higher than those of most temperature-sensing materials. Moreover, the WLED fabricated by Sm 3+ -doped Cs 2 NaInCl 6 :Sb 3+ NCs@PMMA displays CIE color coordinates of (0.30, 0.28), a luminous efficiency of 37.5 lm W −1 , a CCT of 8035 K, and a CRI over 80, which indicate that Sm 3+ -doped Cs 2 NaInCl 6 :Sb 3+ NCs are promising single-component white-light-emitting phosphors for next-generation lighting and display technologies.

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Study of trivalent samarium ion embedded lithium‐based borate glass for high‐density optical memory devices

et al. 2020

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Sm3+ ions doped strontium lithium lead borate glasses (SLLB:Sm) were prepared using a conventional melt‐quenching technique. The glasses were analyzed using X‐ray diffractometry and Fourier transform infrared spectroscopy, optical absorption, fluorescence spectral analysis, and fluorescence lifetime decay. The Judd–Ofelt (J–O) parameters and radiative parameters of the SLLB:Sm10 glass (1.0 mol% Sm3+ ion‐doped glass) were calculated using J–O theory. From the emission spectra, among all the synthesized glass, SLLB:Sm10 glass had the highest emission intensity for 4G5/2→6H11/2 transition (610 nm). Emission parameters, such as stimulated emission cross‐section and optical gain bandwidth, were calculated. For all concentrations of Sm3+ ions, the decay profile showed an exponential nature and decreased when the Sm3+ ion concentration was increased due to a concentration quenching effect. This result suggests that the synthesized SLLB:Sm10 glass could be used for application in high‐density optical memory devices.

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Concentration effect of Sm3+ ions in B2O3–PbO–PbF2–Bi2O3–ZnO glasses – Structural and luminescence investigations

Cited by 154 publications

References 30 publications

Sm3+ Doped Borotellurite Glass: Absorption, Fluorescence and Optical Parameters

Sm3+ Doped Borotellurite Glass: Absorption, Fluorescence and Optical Parameters

Halide Double Perovskite Nanocrystals Doped with Rare‐Earth Ions for Multifunctional Applications

Study of trivalent samarium ion embedded lithium‐based borate glass for high‐density optical memory devices

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