A b s t r a c t : Thiram, a dithiocarbamate fungicide, i s electrochemically active on glassy carbon electrodes in an aqueous medium. An amperometric method developed under optimized conditions produces smooth and reproducible responses, yielding linear calibration curves with a minimum detection limit of 1 . 0~1 0 .~ M, based on the signal-to-noise ratio (SIN) of 3. Application of t h i s methodology for t h e determination of Thiram in water leachates, collected a t various time intervals from a laboratory prepared soil bed, results in reliable results. Additionally, the amount of Thiram in an agricultural bean seed sample is well quantified using this methodology, thus demonstrating the applicability of the proposed amperometric method in real sample analysis. NMR and UV-visible spectroscopic methods confirm the presence of Thiram in the seed sample.K e y W o r d s : amperometry, cyclic voltammetry, dithiocarbamate fungicide.