Org. Chem. Front.
 2023
DOI: 10.1039/d3qo00005b
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Concise synthesis of hemigossypol via sequential palladium-catalyzed regiospecific oxygenations of the naphthalene ring

Jing Jiang
1
,
Yujian Mao
2
,
Yaoyu Lin
3
et al.

Abstract: A total synthetic approach of hemigossypol is described with 10 steps in 9.5 % total yield with the key feature being successive ligand-directed proximal C-H oxygenations. Direct functionalization of the...

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