Condensation Products of Aldehydes and Ketones with o-Aminobenzyl Alcohol and o-Hydroxybenzylamine

Abstract

Aldehydes and Ketones with Benzyl Alcohols and Amines 1875 acetone' and oxygen was bubbled through the solution for three days, acetone being added from time to time to replace that lost by evaporation. The solvent was evaporated and the solid residue extracted with a solution of potassium bicarbonate. Acidification of the carbonate solution, however, yielded no organic acid. Extraction of the residue with 5% sodium hydroxide yielded isodurenol melting at 78-79°.7 The only compound which (7) Hey, J. Chem. See., 1590 (1931). was isolated from the neutral fraction was unchanged enol (4.4 g.

Smart Synthesis of High-Performance Thermosets Based on ortho-Amide–Imide Functional Benzoxazines

“…Benzoxazine is a newly developed thermosetting resin, which can be synthesized by Mannich condensation from phenol, amine, and formaldehyde (Holly and Cope, 1944;Ning and Ishida, 1994). The major advantages of polybenzoxazine include excellent mechanical and thermal properties, low water absorption, high char yield, and low surface free energy (Ishida and Allen, 1996;Ishida and Low, 1997;Kim et al, 1999a,b;Wang et al, 2006;Velez-Herrera and Ishida, 2009;Yagci et al, 2009;Zhang et al, 2012Zhang et al, , 2013.…”

Structurally diverse benzoxazines: synthesis, polymerization, and thermal stability

“…[3] The benzoxazines were first synthesized by Cope and Holly [4] in 1940 by solvent method. Riess et al [5] studied the synthesis and reaction of monofunctional heterocyclic compounds of this kind.…”

Synthesis and Characterization of Substituted Bisbenzoxazine as Potent Antimicrobial Agent

“…These compounds were characterized by FTIR, 1 6'-(cyclohexane-1,1-diyl)bis(3-(4-nitrophenyl-7-methyl)-3,4-dihydro-2H 6'-(cyclohexane-1,1-diyl)bis(3-(4-hydroxyphenyl-7-bromo)-3,4- …”

“…The first benzoxazine compound was synthesized by Holly and Cope in 1944 [1]. Later, the study on benzoxazines and their oligomers was further conducted from the 1950s to 1970s [2][3][4].…”