We report on the synthesis and the superconductivity of Zr 4 Rh 2 O x (x = 0.4, 0.5, 0.6, 0.7, 1.0). These compounds crystallize in the η-carbide structure, which is a filled version of the complex intermetallic Ti 2 Ni structure. We find that in the system Zr 4 Rh 2 O x , already a small amount (x ≥ 0.4) of oxygen addition stabilizes the η-carbide structure over the more common intermetallic CuAl 2 structure-type, in which Zr 2 Rh crystallizes. We show that Zr 4 Rh 2 O 0.7 and Zr 4 Rh 2 O are bulk superconductors with critical temperatures of T c ≈ 2.8 K and 4.7 K in the resistivity, respectively. Our analysis of the superconducting properties reveal both compounds to be strongly type-II superconductors with critical fields up to µ 0 H c1 (0) ≈ 8.8 mT and µ 0 H c2 (0) ≈ 6.08 T. Our results support that the η-carbides are a versatile family of compounds for the investigation of the interplay of interstitial doping on physical properties, especially for superconductivity.