The functionalization
of inexpensive potato protein concentrate
(PPC) is presented as a simple and easily scalable method to produce
bio-based superabsorbent powders. Five nontoxic acylating agents were
evaluated at different reaction temperatures for solvent-free acylation
of the protein. The best results were obtained for succinic anhydride
(SA) and a reaction temperature of 140 °C. These conditions resulted
in efficient functionalization that provided formation of a useful
network, which allowed high uptake of fluids and little material disintegration
during the uptake, that is, due to protein hydrolysis during the functionalization.
The SA-acylated PPC showed increased water and saline swelling capacities
of 600 and 60%, respectively, as compared to untreated PPC. The acylated
potato protein also showed a saline liquid holding capacity of approximately
50% after centrifugation at 1230 rpm for 3 min, as well as a significant
blood swelling capacity of 530%. This blood swelling represents more
than 50% of that of a commercial fossil-based superabsorbent (SAP)
used for blood absorption in sanitary health products. The swelling
properties of these inexpensive protein-based acylated materials highlight
their potential as sustainable SAP materials (from industrial side-streams)
in applications such as daily care products that are currently dominated
by fossil-based SAPs.