2017
DOI: 10.1016/j.snb.2016.10.061
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Conduction mechanisms in SnO2 single-nanowire gas sensors: An impedance spectroscopy study

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Cited by 69 publications
(44 citation statements)
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“…This divergence can be attributed to the sensing mechanism of individual structures, which should be understood by examining the ratio between the material thickness and the Debye length, which is directly related to the amount of exchanged charges [ 40 ]. So, even considering that the total of adsorbed analyte species is larger for Device 2 due to the greater number of free tin ions with exposed lone pairs available to overlap with the NO 2 molecules, both devices are only partially depleted due to the so-called Weisz limitation where the band bending is limited to about 1 eV as a way to prevent the double-layer potential (number of charged species limited to 10 −5 to 10 −3 monolayers) [ 41 , 42 ], causing thickness to play a major role.…”
Section: Discussionmentioning
confidence: 99%
“…This divergence can be attributed to the sensing mechanism of individual structures, which should be understood by examining the ratio between the material thickness and the Debye length, which is directly related to the amount of exchanged charges [ 40 ]. So, even considering that the total of adsorbed analyte species is larger for Device 2 due to the greater number of free tin ions with exposed lone pairs available to overlap with the NO 2 molecules, both devices are only partially depleted due to the so-called Weisz limitation where the band bending is limited to about 1 eV as a way to prevent the double-layer potential (number of charged species limited to 10 −5 to 10 −3 monolayers) [ 41 , 42 ], causing thickness to play a major role.…”
Section: Discussionmentioning
confidence: 99%
“…32 In addition, the interlayer of multilayer expanded graphite could accommodate large volume changes of nanowires, avoiding collapse or deformation during repeated adsorption and desorption. 33 HRTEM images of EG/ NA3 displayed in Fig. 2d-f indicate that the nanowires were formed by nano-sized crystals and the lattice spacings 0.751 and 0.252 nm correspond to the (003) and (012) planes of the NiAl-LDH nanocrystal, respectively; 0.21 nm corresponds to the (002) plane of EG.…”
Section: Morphology and Structure Characterizationsmentioning
confidence: 97%
“…SnO 2 nanowires have been synthesized mainly through a vapor-solid or vapor-liquid-solid process. 18,[20][21][22][23] The disadvantages of these methods are the high temperatures required for synthesis, costly scale-up, and difficulty in synthesizing a reproducible and uniform nanowire. In recent years, the socalled polyol process, which involves the use of ethylene glycol (EG), has been proposed to overcome these disadvantages.…”
Section: Introductionmentioning
confidence: 99%