Confined pyrolysis of a dye pollutant for two-dimensional F,N,S tri-doped nanocarbon as a high performance oxidative coupling reaction catalyst

Abstract

Nanocarbon materials as metal-free catalysts for the oxidative coupling of primary amines to imines suffer from high catalyst loading, low reaction rate and high oxygen demand. Doping heteroatom in nanocarbons...

Catalytic oxidative dehydrogenation of N-heterocycles with nitrogen/phosphorus co-doped porous carbon materials

“…41-1487), respectively. 55 Raman spectra of the samples present the G band at 1587 cm −1 , which is a characteristic feature of graphitic carbon, while the D band at 1339 cm −1 corresponds to defective carbon structures. 56 Notably, the Raman spectra are sensitive to the subtle structural changes of porous carbon materials.…”

Capturing the Hierarchically Assorted Modules of Protein Interaction in the Organized Nucleome

“…The qXL-MS workflow consists of multiple sequentially performing components (Liu et al, 2018b). Once a biological system is chosen for the study of special biological questions, the ultimate interactomic results are basically determined by a combination of the arbitrarily selected wet and dry laboratory methods, ranging from a choice of Chemical crosslinking (1 st C) for identification of XL-peptides to the chemical labeling either of proteins or peptides for quantitation, to the Chromatographic (2 nd C) separation and enrichment of XL-peptides for MS/MS analysis, and finally to the choice of software used for Computational analysis (3 rd C) of MS data and quantitation (See Reviews by Chavez et al, 2016;Yu and Huang, 2018;Matzinger and Mechtler, 2021).…”

“…The copyright holder for this preprint this version posted August 15, 2022. ; https://doi.org/10.1101/2022.08.14.503837 doi: bioRxiv preprint interactomic practice for maintaining the native PPIs at or near native physiological levels (Liu et al, 2018b;Yu et al, 2019). To understand how the formaldehyde prefixation may influence the construction of modulome, we constructed 118 modules and 4 communities using the filtered nuclear 1,398 Arabidopsis orthologous hetero-PPIs (997 protein components) derived from crosslinks of non-formaldehyde-prefixed nuclei samples and compared them with that of formaldehyde-prefixed samples (Table S8a-g; Fig S30A-B).…”

“…Fmocprotected N-terminal amine was used to promote the crosslinking between two peptides at the side chains of lysine. The CBDPS-based crosslinking was performed using a previously described method (Liu et al, 2018b;Zhu et al, 2016b). The XL-peptides were labeled separately with light and heavy CH 2 O using the method described above, followed by desalting with Oasis HLB cartridges and concentrating with SpeedVac.…”

“…Provided with the extensive understanding of roles of nuclear proteins and nucleome organization, it still remains mysterious about how these nuclear proteins collectively partition, interact and organize in nucleome to drive and mediate the dynamic changes of chromosomal folding, 3-D genome organization, the assembly of nuclear body, the formation of biomolecular condensate and HUB of chromatin-RNA interactions, the histone code encryption and code-deciphering and regulation of gene expression. To address some of these questions from a different perspective, we decided to combine the in vivo chemical crosslinking-coupled mass spectrometry (XL-MS) (Iacobucci et al, 2019;Liu et al, 2018b;Yu and Huang, 2018) with a MONET-based (Tomasoni et al, 2020) modulomics to profile nucleomic protein-protein interactions (PPIs) and construct a nuclear protein interaction modulome, consisting of hierarchically and topologically organized protein clusters, complexes, subnuclear compartments (including nucleoli, nuclear condensates and nuclear bodies) and nucleosomes. The in vivo formaldehydefixing of interacting DNA molecules in living cells had been successfully applied in the proximity ligation of DNA fragments (3C, chromatin conformation capture; Hi-C, highthroughput chromosome conformation capture) to elucidate the comprehensive 3-D genome topology and chromatin fiber interactions (Dekker et al, 2002;Nagano et al, 2013;Quinodoz et al, 2018) and to reveal high resolution architecture features and dynamic changes of chromatin loops and TADs in genome organization (Dekker and Mirny, 2016;Lieberman-Aiden et al, 2009;Misteli, 2020).…”