The ultimate limit on fiber loss is set by the intrinsic Rayleigh scattering of silica glass material. Here, we challenge this limit in the visible region by using a hollow-core fiber approach. Two visible-guiding hollow-core conjoined-tube negativecurvature fibers are successfully fabricated and exhibit the overall losses of 3.8 dB/km at 680 nm and 4.9 dB/km at 558 nm respectively. The loss of the latter fiber surpasses the Rayleigh scattering limit of silica glass fiber in the green spectral region by 2 dB. Numerical simulation indicates that this loss level is still much higher than the fundamental surface scattering loss limit of hollow-core fiber.After over 40 years of technological refinement, the Rayleigh scattering loss (RSL), caused by microscopic density fluctuation frozen in bulk glass [1], has become the dominant loss constituent in state-of-the-art silica glass fiber (SGF) throughout most of its operating wavelength. The fact that the RSL is fundamentally insurmountable casts a shadow on future applications of optical fiber ranging from communications to sensing and laser. First, the most efficient light transmission window in a fiber is restricted near 1.55 μm wavelength with the minimum loss of ~ 0.14 dB/km [2] and the bandwidth of some tens of THz [3]. In order to send signals through long distance in a fiber, the carrier wavelength of light usually has to be converted to the telecom band [4], introducing great complexity in the design of long-haul optical fiber systems. Second, the λ −4 wavelength dependence of the RSL is against the trend of employing advanced fiber laser technology in versatile areas, for instance, biochemical imaging and materials-processing, toward shorter and shorter wavelengths for better resolution [5,6].Utilizing fluoride glass or multi-component oxide glass, which is characterized by lower glass transition temperature and thus lower density fluctuation, is expected to reduce the RSL by one order of magnitude, e.g., ~ 0.01 dB/km RSL in fluoride glass at 2.5 µm [7] and ~ 0.05 dB/km RSL in sodium silicate glass at 1.55 μm [8]. However, in realistic fiber drawing, significantly high extrinsic losses from impurity, crystallization, defect, etc, have not yet been overcome [7], leaving these soft glass fibers inferior to SGF in terms of propagation attenuation.Since their first demonstration [9], the possibility that hollow-core photonic bandgap fibers (HC-PBGFs) can bypass the RSL limit of SGF has been highlighted and eagerly anticipated. HC-PBGF fills its core with dry air whose RSL is more than 200 times lower than in silica glass [10].