Conjugated bond polymers with heteroatoms in the conjugated chain—XXI. Polymeric complexes of tetracyanoethylene

Берлин, А. А.; Matveyeva, N.G.; Sherle, A. I.; Kostrova, N.D.

doi:10.1016/0032-3950(63)90438-6

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Polytetracyanoethylene and Polymer-metal Complexes Of Tcne2

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1967

1972

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Cited by 4 publications

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“…The polymerization of TCNE can be effected by various reagents (alcohols, phenols, amines, and amides) at 200°under appropriate conditions (11,14). The polymeric chelate complexes of TCNE have, however, been prepared in the form of thin films (10-4 to 10-5 cm) on metallic surfaces by heating the metal with TCNE in evacuated ampoules at elevated temperatures for prolonged periods (12). The TCNE-metal complexes are formulated to have the phthalocyanine type of structure (XLVII) (8).…”

Section: Polytetracyanoethylene and Polymer-metal Complexes Of Tcnementioning

confidence: 99%

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The Chemistry of Tetracyanoethylene

Dhar¹

1967

Chem. Rev.

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Section: Polytetracyanoethylene and Polymer-metal Complexes Of Tcnementioning

confidence: 99%

“…These complexes are thermostable up to 400-450°, partially crystalline, and semiconductive, and possess enhanced magnetic susceptibility (12). The polymer, as a thin film on metal, has an excellent durability and is unaffected by organic solvents, acids, or alkalis.…”

Section: Polytetracyanoethylene and Polymer-metal Complexes Of Tcnementioning

confidence: 99%