Conjugated cobalt polyphthalocyanine with defective π-π extended structure for enhanced rechargeable li-oxygen batteries

Highly effective bifunctional defective cobalt phthalocyanine for photo-involved lithium-oxygen batteries

“…This result is conducive to oxygen diffusion and electrolyte penetration. 42 UV-vis spectra of D-CoPPc, CoPPc and CoPc also support the above conclusions (Fig. S4 †).…”

“…The structural defects in the materials facilitate the separation and migration of photo-induced carriers, and photogenerated electrons and holes accelerate the ORR and OER processes, respectively. 42,[47][48][49] The LOBs assembled with three cathodes (CoPc/CNT, CoPPc/ CNT and D-CoPPc/CNT) were discharged/charged in the voltage range of [2.5, 3.1 V]/[3.1, 4.0 V], and the LSV curves were recorded in Fig. 3a,b.…”

“…S13 † further veries its excellent chemical stability. 42 In summary, the aid of light in LOBs has signicant advantages for the improvement of battery performance. Among the three materials, D-CoPPc/CNT has the best rate performance and cycle stability.…”

Boosting aqueous non-flow zinc–bromine batteries with a two-dimensional metal–organic framework host: an adsorption-catalysis approach

“…For comparison purposes, a control group using polyphthalocyanine (PPc) was established without the inclusion of metal chlorides. 27 The synthesis routine of NiPPc and PPc is illustrated in Fig. S1 (ESI †) in detail, and the structure and energy storage mechanism of NiPPc is depicted in Fig.…”

Surface Enrichment of Redox Mediator for Long-Cyclable Lithium–Air Batteries

“…Since the very beginning of Li–air batteries research, anchored (by heat treatment, π–π stacking, or polymerization) metal phthalocyanines have been utilized as solid-state ORR/OER catalysts at the air cathode. − In recent years, solution-phase metal phthalocyanines ,,− and porphyrins − have also been successfully used as RMs in Li–air/Li–O 2 batteries. In most reports, neat metal phthalocyanines/porphyrins were used, leaving the effect of side substituent groups on the RM behavior and battery performance yet to be explored.…”