Conjugated Thermolysis of Metal-Containing Monomers: Toward Core–Shell Nanostructured Advanced Materials

Preparation of Copper‐containing Nanocomposites by Thermolysis of Copper (II) Complex and Their Use as Anti‐friction and Anti‐wear Additives to Lubricant Oils

“…Among a wide variety of methods for producing nanomaterials, one of the simplest and cheapest approaches is thermolysis of metal compounds, which makes it possible to obtain monodisperse NPs with small defects in the crystal structure and controlled forms [21–24] . In addition, thermolysis is characterized by cost‐effectiveness and environmental friendliness, the ability to easily control the synthesis conditions, the absence of the need for special equipment, complex technological processes, and difficult synthesis conditions [25–27] . The main requirements for metal‐containing precursors include high purity, ease of handling, storage convenience, non‐toxicity, decomposition at low temperatures, etc.…”

“…[21][22][23][24] In addition, thermolysis is characterized by cost-effectiveness and environmental friendliness, the ability to easily control the synthesis conditions, the absence of the need for special equipment, complex technological processes, and difficult synthesis conditions. [25][26][27] The main requirements for metal-containing precursors include high purity, ease of handling, storage convenience, non-toxicity, decomposition at low temperatures, etc.…”

Silver Itaconate as Single-Source Precursor of Nanocomposites for the Analysis of Chloride Ions

“…Recently, active research has been conducted on the thermolysis of metal-containing monomers, where MCMs function as single-source precursors for obtaining nanocomposite materials in which metal nanoparticles (NPs) are stabilized by a carbon or polymer shell [ 33 , 34 ]. Silver NPs favorably stand out among various metal NPs because of the manifestation of a wide range of properties: outstanding plasmonic activity, antibacterial activity, chemical stability, good thermal and electrical conductivity, and catalytic activity [ 35 , 36 , 37 , 38 , 39 ].…”

FeCo@N‐Doped Nanoparticles Encapsulated in Polyacrylamide‐Derived Carbon Nanocages as a Functional Filler for Polyethylene System

“…Currently, there is considerable interest in the production of double or multicomponent composite materials to improve their functional properties due to the synergy of each individual chemical. [1][2][3][4][5] Magnetic carbon-based composites have played an important role in recent development in the case of many functional materials, including microwave absorbing materials (MAMs) to reduce electromagnetic pollution, information security and military stealth technology, [6,7] electrode addictive and substrates for electrochemical batteries, [8] a catalyst system for oxygen evolution and reduction reactions in metal-air batteries, as well as fuel cells. [9] The main characteristics that determine their design and performance relate to compatible magnetic and dielectric losses, controlled chemistry and spatial organization, which can be an effective customizable approach to achieve the target final functionality.…”

“…[17] In another interesting example, thermolysis of FeCo Prussian Blue analogues coated with polydopamine (PDA) resulted in core-shell FeCo@C NPs, in which PDAderived carbon nanocages showed a lower level of crystallinity compared to inner carbon-shells, forming a unique hierarchical configuration. [5] Moreover, the carbon shell can stabilize the spatial structure, suppressing negative skin effects, and can create interfaces that are non-uniform enough to cause a significant improvement in reflection loss performance. Among the various methods, one of the most promising is based on the polymer-mediated synthesis of matrix-stabilized metal NPs, in particular, frontal polymerization of metal-containing monomers followed by controlled thermolysis of the resulting products, as recently published by G. Dzhardimalieva.…”